二氯化双(正丁基环成二烯基)锆
Bis(n-butylcyclopentadienyl)zirkonium dichloride
CAS: 73364-10-0
Molecular Formula: C18H26Cl2Zr
二氯化双(正丁基环成二烯基)锆 - Names and Identifiers
| Name | Bis(n-butylcyclopentadienyl)zirkonium dichloride |
| Synonyms | Bisnbutylcyclopentadienylzirconiumdichloridemin Bis(n-butylcyclopentadienyl)zirkonium dichloride Bis(n-butylcyclopentadienyl)zirconium dichloride |
| CAS | 73364-10-0 |
| EINECS | 416-980-1 |
| InChI | InChI=1/2C9H13.2ClH.Zr/c2*1-2-3-6-9-7-4-5-8-9;;;/h2*4-5,7-8H,2-3,6H2,1H3;2*1H;/q;;;;+2/p-2/r2C9H13.Cl2Zr/c2*1-2-3-6-9-7-4-5-8-9;1-3-2/h2*4-5,7-8H,2-3,6H2,1H3 |
二氯化双(正丁基环成二烯基)锆 - Physico-chemical Properties
| Molecular Formula | C18H26Cl2Zr |
| Molar Mass | 404.53 |
| Melting Point | 97-102℃ |
| Storage Condition | 2-8℃ |
二氯化双(正丁基环成二烯基)锆 - Risk and Safety
| Hazard Symbols | C - Corrosive |
| Risk Codes | R34 - Causes burns |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
二氯化双(正丁基环成二烯基)锆 - Bis (n-butylcyclopentadienyl) zirconium dichloride/methylaluminoxane catalyzed oligomerization of 1-butene
From VIP Journal Professional Edition
Author:
Jiang Tao ,< a href = "https://xueshu.baidu.com/usercenter/data/author?cmd=authoruri&wd=authoruri:(3 dc2e59391c79413) author:(Chen Meichao)" target = "_blank"> Chen Meichao ,< a href = "https://xueshu.baidu.com/usercenter/data/author?cmd=authoruri&wd=authoruri:(f50674768fa07a8a) author:(Shao Huaiqi)" target = "_blank">/a>
Summary:
bis (n-butylcyclopentadienyl) zirconium dichloride/methylaluminoxane (MAO) was used to catalyze the oligomerization of 1-butene. the effects of reaction temperature, n(Al):n(Zr), promoter type and reaction time on the catalytic activity and distribution of oligomerization products were investigated, and the optimal process conditions for the oligomerization of 1-butene were determined. After the solvent and dimer were removed by vacuum distillation, the branching degree (BI) of the remaining fraction was 0.312,5 and the double bond value was 1.905 mmol/g by 1H NMR analysis. At 20 ℃, the kinematic viscosity is 5.8,mm2/s, and the density is 0.822,8,g/cm3. The remaining fraction after removing the solvent and dimer is suitable for use as diesel.
keywords:
metallocene catalyst; 1-butene; oligomerization reaction; diesel
DOI:
10.3969/j.issn.1672-6510.2013.03.005
cited:
Year:
2013
Last Update：2024-01-02 23:10:35
二氯化双(正丁基环成二烯基)锆 - Zirconium dichloride-catalyzed oligomerization of 1-butene
from Baidu library
Author:
ning ying male , Li meijiao , 1-butene; oligomerization; catalyst
DOI:
10.3969/j.issn.1002-1124.2014.03.022
cited:
Year:
2014
Last Update：2023-08-16 22:23:51
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