(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - Names and Identifiers
Name | 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
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Synonyms | (S,S)-ME-BPE-RH (à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh
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CAS | 213343-65-8
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - Physico-chemical Properties
Molecular Formula | C22H40BF4P2Rh-
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Molar Mass | 556.21 |
Melting Point | 152.2-156.3°C |
Appearance | Crystalline Powder |
Color | Orange to red to brown |
Sensitive | air sensitive |
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - Risk and Safety
Hazard Symbols | Xi - Irritant
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Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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WGK Germany | 3 |
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - Introduction
1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is an organometallic complex. The following is a description of its nature, use, preparation and safety information:
Nature:
-Chemical formula: C25H44BF4P2Rh
-Molecular weight: 569.17g/mol
-Appearance: White powder
-melting point: about 100 degrees Celsius
-Solubility: Soluble in some organic solvents
Use:
- 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane (1,5-cyclootadiene) rhodium(I) tetrafluoroborate are often used as catalysts and play an important role in organic synthesis reactions.
-It can be used for asymmetric catalytic reactions to generate organic molecules with high stereoselectivity.
-The complex is often used in the synthesis of organometallic complexes and is widely used in the field of organic synthesis.
Preparation Method:
1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is prepared by the following steps:
1. first synthesis of cyclooctadiene ligand.
2. according to the requirements of the synthesis of phosphorus ligands.
3. The rhodium (I) salt and the ligand are coordinated and reacted in an appropriate solvent.
4. Finally, tetrafluoroboric acid was used to give stability to the complex and purification was carried out.
Safety Information:
There is limited safety information about the 1,2-Bis((2S,5S)-2,5-dimenthylphospholano) ethane (1,5-cycloctadiene) rhodium(I) tetrafluoroborate, so it is necessary to take appropriate laboratory safety measures during operation. When using and handling complexes, it is recommended to follow the safe operating procedures of the organic synthesis laboratory and follow the safety precautions of the relevant chemicals.
Please note that this is only a brief introduction to the rhodium(I) tetrafluoroborate of 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclo-ctadiene). Relevant literature and guidelines are also required for specific use and operation.
Last Update:2024-04-10 22:29:15