(E)-prop-1-en-1-ylMagnesiuM broMide
1-propenylmagnesium bromide
CAS: 14092-04-7
Molecular Formula: C3H5BrMg
(E)-prop-1-en-1-ylMagnesiuM broMide - Names and Identifiers
(E)-prop-1-en-1-ylMagnesiuM broMide - Physico-chemical Properties
| Molecular Formula | C3H5BrMg |
| Molar Mass | 145.28 |
| Density | 0.95g/mLat 25°C |
| Boling Point | 65°C |
| Flash Point | −4°F |
| Vapor Presure | 8480mmHg at 25°C |
| Appearance | Solution |
| Color | Light yellow to orange to brown |
| Storage Condition | 2-8°C |
(E)-prop-1-en-1-ylMagnesiuM broMide - Risk and Safety
| Risk Codes | R11 - Highly Flammable R14/15 - R19 - May form explosive peroxides R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R34 - Causes burns R37 - Irritating to the respiratory system R40 - Limited evidence of a carcinogenic effect R36/37/38 - Irritating to eyes, respiratory system and skin. R15 - Contact with water liberates extremely flammable gases |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S36/37 - Wear suitable protective clothing and gloves. |
| UN IDs | UN 3399 4.3/PG 1 |
| WGK Germany | 3 |
| HS Code | 29319090 |
(E)-prop-1-en-1-ylMagnesiuM broMide - Introduction
1-propyl magnesium bromide is an organic compound with the chemical formula C3H7MgBr. The following is a description of its nature, use, preparation and safety information:
Nature:
-Appearance: 1-propylmagnesium bromide is a colorless to pale yellow liquid.
-Solubility: Soluble in ether, ethanol and dimethylformamide, insoluble in water.
-Melting point: approximately at -50°C.
-Boiling point: Under normal pressure, its boiling point is about 110°C.
Use:
- 1-propyl magnesium bromide is commonly used as a reagent in organic synthesis.
-It can be used as an alkylation reagent in organic synthesis, and is often used to introduce propyl groups.
-It can also be used as a catalyst to promote the reaction of certain organic compounds.
Preparation Method:
-1-propylmagnesium bromide is generally obtained by reacting ethyl bromide with metallic magnesium. The reaction conditions can be carried out in the presence of a drying agent, such as a drying agent 4Å molecular sieve, and the reaction temperature is usually from room temperature to 35°C.
-The reaction equation is as follows: C3H7Br Mg → C3H7MgBr.
Safety Information:
- 1-propyl magnesium bromide is dangerous, is an organic compound. Contact with skin, eyes or inhalation of its vapors may cause irritation.
-use should wear protective glasses, gloves, protective clothing and other personal protective equipment.
-Pay attention to a well-ventilated environment during operation and avoid inhaling its vapor.
-In case of skin or eye contact, rinse immediately with plenty of water and seek medical assistance.
-Store 1-propylmagnesium bromide in a dry, ventilated place away from sources of ignition or heat.
Nature:
-Appearance: 1-propylmagnesium bromide is a colorless to pale yellow liquid.
-Solubility: Soluble in ether, ethanol and dimethylformamide, insoluble in water.
-Melting point: approximately at -50°C.
-Boiling point: Under normal pressure, its boiling point is about 110°C.
Use:
- 1-propyl magnesium bromide is commonly used as a reagent in organic synthesis.
-It can be used as an alkylation reagent in organic synthesis, and is often used to introduce propyl groups.
-It can also be used as a catalyst to promote the reaction of certain organic compounds.
Preparation Method:
-1-propylmagnesium bromide is generally obtained by reacting ethyl bromide with metallic magnesium. The reaction conditions can be carried out in the presence of a drying agent, such as a drying agent 4Å molecular sieve, and the reaction temperature is usually from room temperature to 35°C.
-The reaction equation is as follows: C3H7Br Mg → C3H7MgBr.
Safety Information:
- 1-propyl magnesium bromide is dangerous, is an organic compound. Contact with skin, eyes or inhalation of its vapors may cause irritation.
-use should wear protective glasses, gloves, protective clothing and other personal protective equipment.
-Pay attention to a well-ventilated environment during operation and avoid inhaling its vapor.
-In case of skin or eye contact, rinse immediately with plenty of water and seek medical assistance.
-Store 1-propylmagnesium bromide in a dry, ventilated place away from sources of ignition or heat.
Last Update：2024-04-10 22:29:15
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