(Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine
2-(Tributylstannyl)pyrimidine
CAS: 153435-63-3
Molecular Formula: C16H30N2Sn
(Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine - Names and Identifiers
| Name | 2-(Tributylstannyl)pyrimidine |
| Synonyms | 2-tributyltinpyrMidine Tributyl(2-pyrimidyl)stannane 2-(Tributylstannyl)pyrimidine PyriMidine,2-(tributylstannyl)- 2-(Tributylstannanyl)pyrimidine 2-(tri-n-butylstannyl)pyrimidine tributyl(pyrimidin-2-yl)stannane (Pyrimidin-2-yl)tributylstannane (Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine |
| CAS | 153435-63-3 |
| InChI | InChI=1/C4H3N2.3C4H9.Sn/c1-2-5-4-6-3-1;3*1-3-4-2;/h1-3H;3*1,3-4H2,2H3;/rC16H30N2Sn/c1-4-7-13-19(14-8-5-2,15-9-6-3)16-17-11-10-12-18-16/h10-12H,4-9,13-15H2,1-3H3 |
(Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine - Physico-chemical Properties
| Molecular Formula | C16H30N2Sn |
| Molar Mass | 369.13 |
| Density | 1.164 g/mL at 25 °C |
| Boling Point | 381.2±25.0 °C(Predicted) |
| Flash Point | >110℃ |
| Vapor Presure | 0mmHg at 25°C |
| pKa | 1.42±0.33(Predicted) |
| Storage Condition | Sealed in dry,2-8°C |
| Refractive Index | n20/D1.512 |
| Physical and Chemical Properties | Storage Conditions: Keep Cold |
(Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine - Risk and Safety
| Risk Codes | R21 - Harmful in contact with skin R25 - Toxic if swallowed R36/38 - Irritating to eyes and skin. R48/23/25 - R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S35 - This material and its container must be disposed of in a safe way. |
| UN IDs | UN 2788 6.1 / PGIII |
| WGK Germany | 3 |
| HS Code | 29339900 |
| Hazard Class | IRRITANT, TOXIC, KEE |
(Pyrimidin-2-yl)tributylstannane, 2-(Tributylstannyl)-1,3-diazine - Introduction
2-(Tributylstannyl)pyrimidine is an organotin compound with the chemical formula C15H30N2Sn. The following is a brief description of its nature, use, preparation and safety information:
Properties: 2-(Tributylstannyl)pyrimidine is a colorless to light yellow solid, soluble in organic solvents such as ether and benzene. It is stable and relatively difficult to decompose at room temperature.
Uses: 2-(Tributylstannyl)pyrimidine is commonly used as a catalyst, especially in the synthesis of organic compounds. It can catalyze the hydroxymethylation reaction of olefins, as well as the pentadienylation reaction of cyclic compounds. In addition, it is also used in the synthesis of fungicides and bioactive molecules.
Preparation Method: Synthesis of 2-(Tributylstannyl)pyrimidine is usually obtained by reacting tributyltin chloride ((C4H9)3SnCl) with pyrimidine. During the reaction, it is usually necessary to use basic conditions, inert solvents and appropriate reaction temperatures.
Safety Information: 2-(Tributylstannyl)pyrimidine should be followed by safe procedures to avoid inhalation, ingestion or contact with skin and eyes. Wear suitable protective gloves, glasses and laboratory clothing during handling. Carefully read and follow the relevant safety instructions before use. Due to the characteristics of its organotin compounds, it may be toxic and harmful to the environment, and the waste should be properly treated and disposed. If necessary, comply with local, regional or national regulations and guidelines.
Properties: 2-(Tributylstannyl)pyrimidine is a colorless to light yellow solid, soluble in organic solvents such as ether and benzene. It is stable and relatively difficult to decompose at room temperature.
Uses: 2-(Tributylstannyl)pyrimidine is commonly used as a catalyst, especially in the synthesis of organic compounds. It can catalyze the hydroxymethylation reaction of olefins, as well as the pentadienylation reaction of cyclic compounds. In addition, it is also used in the synthesis of fungicides and bioactive molecules.
Preparation Method: Synthesis of 2-(Tributylstannyl)pyrimidine is usually obtained by reacting tributyltin chloride ((C4H9)3SnCl) with pyrimidine. During the reaction, it is usually necessary to use basic conditions, inert solvents and appropriate reaction temperatures.
Safety Information: 2-(Tributylstannyl)pyrimidine should be followed by safe procedures to avoid inhalation, ingestion or contact with skin and eyes. Wear suitable protective gloves, glasses and laboratory clothing during handling. Carefully read and follow the relevant safety instructions before use. Due to the characteristics of its organotin compounds, it may be toxic and harmful to the environment, and the waste should be properly treated and disposed. If necessary, comply with local, regional or national regulations and guidelines.
Last Update：2024-04-10 22:29:15
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