(η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2
(η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2
CAS: 145519-50-2
Molecular Formula: C19H23Cl2NSiZr
(η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2 - Names and Identifiers
| Name | (η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2 |
| CAS | 145519-50-2 |
(η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2 - Physico-chemical Properties
| Molecular Formula | C19H23Cl2NSiZr |
| Molar Mass | 455.61 |
(η(5):η(1)-C13H8SiMe2N(t)Bu)ZrCl2 - Introduction
(η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is an organic compound which is a complex of a zirconium atom and a ligand (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu). The following is a description of the properties, uses, preparation and safety information of the compound:
Nature:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is a solid, usually yellow or orange crystal.
-The complex has high thermal stability and solubility.
Use:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is commonly used as a catalyst, especially in organic synthesis and asymmetric catalytic reactions.
-It can catalyze the carbonyl addition reaction between olefins and aliphatic aldehydes/ketones, the Michael addition reaction between olefins and isocyanates, and other related transfer addition reactions.
Preparation Method:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is generally synthesized by reacting a chloride whose coordination atom is zirconium with a ligand having a corresponding coordination site.
-Zirconium chloride reacts with (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu) ligand under appropriate reaction conditions to obtain (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2.
Safety Information:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 may cause health hazards, so appropriate protective measures should be taken during operation or use.
-contact with skin and eyes should be washed immediately with plenty of water.
-in use should be careful to avoid inhalation of its dust or vapor.
-Waste material should be disposed of in accordance with local regulations.
Nature:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is a solid, usually yellow or orange crystal.
-The complex has high thermal stability and solubility.
Use:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is commonly used as a catalyst, especially in organic synthesis and asymmetric catalytic reactions.
-It can catalyze the carbonyl addition reaction between olefins and aliphatic aldehydes/ketones, the Michael addition reaction between olefins and isocyanates, and other related transfer addition reactions.
Preparation Method:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 is generally synthesized by reacting a chloride whose coordination atom is zirconium with a ligand having a corresponding coordination site.
-Zirconium chloride reacts with (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu) ligand under appropriate reaction conditions to obtain (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2.
Safety Information:
- (η ^ 5:η ^ 1-C13H8SiMe2N(t)Bu)ZrCl2 may cause health hazards, so appropriate protective measures should be taken during operation or use.
-contact with skin and eyes should be washed immediately with plenty of water.
-in use should be careful to avoid inhalation of its dust or vapor.
-Waste material should be disposed of in accordance with local regulations.
Last Update：2024-04-09 20:49:11
