1,3-双(1-金刚烷基)氯化咪唑 - Names and Identifiers
Name | 1,3-BIS(1-ADAMANTYL)IMIDAZOLIUM CHLORIDE
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Synonyms | 1,3-DIADAMANTYL-IMIDAZOLIUM CHLORIDE 1,3-BIS(1-ADAMANTYL)IMIDAZOLIUM CHLORIDE 1,3-BIS(ADAMANT-1-YL)IMIDAZOLIUM CHLORIDE 1,3-Bis(1-adamantanyl)imidazolium chloride 1,3-BIS(1-ADAMANTYL)IMIDAZOLIUM CHLORIDE, MIN 1,3-Di(adaMantan-1-yl)-1H-iMidazol-3-iuM chloride 1,3-ditricyclo[3.3.1.1~3,7~]dec-1-yl-1H-imidazol-3-ium 1,3-Bis(adamant-1-yl)-1,3-dihydro-2H-imidazol-2-ylidene monohydrochloride
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CAS | 131042-78-9
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InChI | InChI=1/C23H33N2/c1-2-25(23-12-19-6-20(13-23)8-21(7-19)14-23)15-24(1)22-9-16-3-17(10-22)5-18(4-16)11-22/h1-2,15-21H,3-14H2/q+1 |
1,3-双(1-金刚烷基)氯化咪唑 - Physico-chemical Properties
Molecular Formula | C23H33ClN2
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Molar Mass | 372.97 |
Melting Point | 345-346°C |
Appearance | crystal |
Color | white |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Stability | hygroscopic |
1,3-双(1-金刚烷基)氯化咪唑 - Risk and Safety
Hazard Symbols | Xi - Irritant
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Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin.
R36/37 - Irritating to eyes and respiratory system.
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Safety Description | S37/39 - Wear suitable gloves and eye/face protection
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
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1,3-双(1-金刚烷基)氯化咪唑 - Introduction
1,3-bis (1-adamantyl) imidazolium chloride, also abbreviated as BICl, is an organic compound. The following is a description of its nature, use, preparation and safety information:
Nature:
-Appearance: 1,3-bis (1-adamantyl) imidazole chloride is a colorless to slightly yellow liquid;
-Solubility: It can be dissolved in organic solvents such as ethanol, methanol and dimethylformamide;
-Stability: It is relatively stable at room temperature, but may decompose at high temperatures.
Use:
1,3-Bis (1-adamantyl) imidazolium chloride has many uses in the chemical field, including:
-Reaction reagent: It can be used as a chlorination reagent in organic synthesis, and can participate in chlorination reaction or catalyze other reactions;
-Ligand: It can form complexes with transition metals for the preparation of catalysts;
-Non-metallic cation probe: It can be used to detect and determine some non-metallic cations.
Preparation Method:
1,3-Bis (1-adamantyl) imidazole chloride can be prepared by the following steps:
1. First, 1-adamantyl imidazole is reacted with thionyl chloride to generate 1-adamantyl imidazole sulfoxide;
2. Next, 1-adamantylimidazolium sulfoxide is reacted with hydrogen chloride in a reaction solvent to produce 1,3-bis (1-adamantyl) imidazolium chloride.
Safety Information:
- 1,3-bis (1-adamantyl) imidazole chloride should pay attention to safety measures when using and handling, such as wearing appropriate protective gloves, goggles and protective clothing;
-After contact with skin or eyes, rinse immediately with plenty of water. In case of discomfort, seek medical attention in time;
-It should be stored in a cool, dry and well-ventilated place, away from fire and oxidants;
-If taken by mistake or inhaled, seek medical attention immediately.
Last Update:2024-04-09 21:01:54