1150112-42-7
Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II) tetrafluoroborate
CAS: 1150112-42-7
Molecular Formula: C50H46BClF4N2P2Ru
1150112-42-7 - Names and Identifiers
| Name | Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II) tetrafluoroborate |
| Synonyms | ][(1R,2R)-cycL oro[(R)-2,2'-bis(diphenyL ohexane-1,2-diamine)]ruthenium(II) tetrafL Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II)tetrafluoroborate Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II) tetrafluoroborate |
| CAS | 1150112-42-7 |
1150112-42-7 - Physico-chemical Properties
| Molecular Formula | C50H46BClF4N2P2Ru |
| Molar Mass | 960.2 |
| Appearance | solid |
| Color | orange |
1150112-42-7 - Introduction
Chloro[(R)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II) tetrafluoroborate, also known as hexafluoroborate chloride [(R)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-cyclohexane-1,2-diamine)]ruthenium(II).
Nature:
This compound is a metal-organic complex whose chemical formula is [RuCl{[(R)-BINAP}(NH_2CH(C_6H_10))]BF_4. It is solid and pale yellow in color. In a solvent, the complex gives off a pineapple-like fragrance.
Use:
This complex is a catalyst and is commonly used in asymmetric catalytic reactions, such as asymmetric hydrogenation, asymmetric hydrogenation, epoxidation, oxidation, etc. It has a wide range of applications in organic synthesis and can be used to generate chiral compounds.
Preparation Method:
The synthesis of the complex can be obtained by reacting oxalic acid [RuCl_3(NH_3)_3] and (R)- 2,2 '-bis (diphenylphosphine)-1,1'-binaphthyl. The reaction process needs to be carried out in tetrahydrofuran (THF) and an excess of cuprous chloride (CuCl) is added as a catalyst.
Safety Information:
The safety of this compound is high, and its solid and solution belong to low toxicity. However, please note that it is still a hazardous substance and should comply with the safety regulations and regulations for laboratory operations. Avoid contact with skin and eyes when handling this compound and wear appropriate personal protective equipment. Observe local environmental codes and regulations when storing and handling outside the laboratory.
Nature:
This compound is a metal-organic complex whose chemical formula is [RuCl{[(R)-BINAP}(NH_2CH(C_6H_10))]BF_4. It is solid and pale yellow in color. In a solvent, the complex gives off a pineapple-like fragrance.
Use:
This complex is a catalyst and is commonly used in asymmetric catalytic reactions, such as asymmetric hydrogenation, asymmetric hydrogenation, epoxidation, oxidation, etc. It has a wide range of applications in organic synthesis and can be used to generate chiral compounds.
Preparation Method:
The synthesis of the complex can be obtained by reacting oxalic acid [RuCl_3(NH_3)_3] and (R)- 2,2 '-bis (diphenylphosphine)-1,1'-binaphthyl. The reaction process needs to be carried out in tetrahydrofuran (THF) and an excess of cuprous chloride (CuCl) is added as a catalyst.
Safety Information:
The safety of this compound is high, and its solid and solution belong to low toxicity. However, please note that it is still a hazardous substance and should comply with the safety regulations and regulations for laboratory operations. Avoid contact with skin and eyes when handling this compound and wear appropriate personal protective equipment. Observe local environmental codes and regulations when storing and handling outside the laboratory.
Last Update：2024-04-10 22:29:15
