174467-31-3
(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene
CAS: 174467-31-3
Molecular Formula: C52H48FeN2P2
174467-31-3 - Names and Identifiers
| Name | (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene |
| Synonyms | ]-2,2'-bis(diphenyL (SP,S'P)-1,1'-Bis[(R)-aL (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe (2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (S,S)Fc-1,1'- Bis(diphenylphosphino)-2,2'- bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]fer rocene |
| CAS | 174467-31-3 |
174467-31-3 - Physico-chemical Properties
| Molecular Formula | C52H48FeN2P2 |
| Molar Mass | 818.76 |
| Specific Rotation(α) | -320.0° (c 1.0, CHCl3) |
| Appearance | solid |
| Color | orange-red |
| Stability | store cold |
174467-31-3 - Risk and Safety
| WGK Germany | 3 |
174467-31-3 - Introduction
(SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene is a chiral organic compound that is commonly used as a catalyst for chiral ligands in metal-catalyzed reactions. The following is a description of the properties, uses, preparation and safety information of this compound:
Nature:
-Appearance: colorless crystal
-Molecular formula: C44H40FeP2N2
-Molecular weight: 688.69g/mol
-Solubility: Soluble in common organic solvents such as dimethylformamide (DMF) and dichloromethane
Use:
(SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene as a chiral ligand has important applications in metal-catalyzed reactions. It can cooperate with transition metals to form chiral metal acid catalysts, which are widely used in hydrogenation, oxidation, asymmetric catalytic reactions of olefins and aldehydes and ketones. The chiral characteristics of the compound make it have higher stereoselectivity and reaction efficiency.
Preparation Method:
(SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene can be obtained by chemical synthesis. One common synthetic route is to react ferrocenyl ferric chloride with (R)-α-(dimethylamino) benzyl alcohol to give (R)-α-(dimethylamino) benzylferrocene. This intermediate is then reacted with diphenylphosphine in the presence of a base to give the desired product.
Safety Information:
Safety information related to the (SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene has not been reported in detail. However, as a chemical, attention should be paid to the safety risks of hazardous substances, toxicity and flammability that may be generated during operation. When in use, follow laboratory safety practices, ensure personal protective measures, and properly store and handle the compound.
Nature:
-Appearance: colorless crystal
-Molecular formula: C44H40FeP2N2
-Molecular weight: 688.69g/mol
-Solubility: Soluble in common organic solvents such as dimethylformamide (DMF) and dichloromethane
Use:
(SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene as a chiral ligand has important applications in metal-catalyzed reactions. It can cooperate with transition metals to form chiral metal acid catalysts, which are widely used in hydrogenation, oxidation, asymmetric catalytic reactions of olefins and aldehydes and ketones. The chiral characteristics of the compound make it have higher stereoselectivity and reaction efficiency.
Preparation Method:
(SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene can be obtained by chemical synthesis. One common synthetic route is to react ferrocenyl ferric chloride with (R)-α-(dimethylamino) benzyl alcohol to give (R)-α-(dimethylamino) benzylferrocene. This intermediate is then reacted with diphenylphosphine in the presence of a base to give the desired product.
Safety Information:
Safety information related to the (SP,S'P)-1,1 '-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene has not been reported in detail. However, as a chemical, attention should be paid to the safety risks of hazardous substances, toxicity and flammability that may be generated during operation. When in use, follow laboratory safety practices, ensure personal protective measures, and properly store and handle the compound.
Last Update：2024-04-10 22:29:15
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