3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN
3-methoxyphenylmagnesium bromide
CAS: 36282-40-3
Molecular Formula: C7H7BrMgO
3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN - Names and Identifiers
| Name | 3-methoxyphenylmagnesium bromide |
| Synonyms | 3-METHOXYPHENYLMAGNESIUM BROMIDE 3-methoxyphenylmagnesium bromide Magnesium,bromo(3-methoxyphenyl)- 3-methoxyphenylmagnesium bromide solution 3-Methoxyphenylmagnesium bromide solution 1.0 in THF 3-Methoxyphenylmagnesium bromide 1.0 M solution in THF 3-MethoxyphenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal 3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN |
| CAS | 36282-40-3 |
| InChI | InChI=1/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h2-3,5-6H,1H3;1H;/q;;+1/p-1/rC7H7BrMgO/c1-10-7-4-2-3-6(5-7)9-8/h2-5H,1H3 |
| InChIKey | AJKNYEHIJAMGHX-UHFFFAOYSA-M |
3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN - Physico-chemical Properties
| Molecular Formula | C7H7BrMgO |
| Molar Mass | 211.34 |
| Density | 1.013g/mLat 25°C |
| Boling Point | 65-67°C |
| Flash Point | −4°F |
| Appearance | Solution |
| Color | Clear yellow-brown |
| Sensitive | Air & Moisture Sensitive |
3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN - Risk and Safety
| Risk Codes | R11 - Highly Flammable R14 - Reacts violently with water R19 - May form explosive peroxides R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R34 - Causes burns R37 - Irritating to the respiratory system R40 - Limited evidence of a carcinogenic effect |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 2924 3/PG 2 |
| WGK Germany | 3 |
| HS Code | 29319090 |
| Hazard Class | 3 |
3-METHOXYPHENYLMAGNESIUM BROMIDE, 1.0M S OLUTION IN TETRAHYDROFURAN - Introduction
3-methoxyphenylmagnesium bromide is an organic compound with the chemical formula C7H7BrMgO. Its main properties are as follows:
1. Appearance: 3-methoxygenylmagnesium bromide is a colorless or slightly yellow liquid.
2. Melting point and boiling point: It has no clearly defined melting point and boiling point, and is usually used in solvent-free form at low temperatures.
3. Solubility: 3-methoxygenylmagnesium bromide is soluble in organic solvents such as ethers and alkanes.
4. Reactivity: It is an alkyl magnesium halide, which can react with acids, alcohols, ketones, aldehydes and other compounds to generate the corresponding products.
The main use of 3-methoxygenylmagnesium bromide is as a reagent for organic synthesis reactions. It can be used in the synthesis of aromatic alcohols, ketones, aldehydes and carboxylic acids and other compounds. It is often used in Grignard reactions, can react with halogenated hydrocarbons, acid chlorides and ketones and other substrates to generate carbon-carbon bonds, and can extend the carbon chain.
A common method for preparing 3-methoxypenylmagnesium bromide is to react 3-methoxybromobenzene magnesium bromide with lithium powder in dry ether to generate 3-methoxypenylmagnesium bromide.
Regarding safety information, 3-methoxygenylmagnesium bromide is an organic substance and has a certain degree of danger. During operation, it is necessary to take appropriate protective measures, such as wearing protective glasses and gloves, to avoid direct contact with skin and eyes. At the same time, it should be stored in a dry, ventilated and away from fire sources to avoid oxidation and combustion.
1. Appearance: 3-methoxygenylmagnesium bromide is a colorless or slightly yellow liquid.
2. Melting point and boiling point: It has no clearly defined melting point and boiling point, and is usually used in solvent-free form at low temperatures.
3. Solubility: 3-methoxygenylmagnesium bromide is soluble in organic solvents such as ethers and alkanes.
4. Reactivity: It is an alkyl magnesium halide, which can react with acids, alcohols, ketones, aldehydes and other compounds to generate the corresponding products.
The main use of 3-methoxygenylmagnesium bromide is as a reagent for organic synthesis reactions. It can be used in the synthesis of aromatic alcohols, ketones, aldehydes and carboxylic acids and other compounds. It is often used in Grignard reactions, can react with halogenated hydrocarbons, acid chlorides and ketones and other substrates to generate carbon-carbon bonds, and can extend the carbon chain.
A common method for preparing 3-methoxypenylmagnesium bromide is to react 3-methoxybromobenzene magnesium bromide with lithium powder in dry ether to generate 3-methoxypenylmagnesium bromide.
Regarding safety information, 3-methoxygenylmagnesium bromide is an organic substance and has a certain degree of danger. During operation, it is necessary to take appropriate protective measures, such as wearing protective glasses and gloves, to avoid direct contact with skin and eyes. At the same time, it should be stored in a dry, ventilated and away from fire sources to avoid oxidation and combustion.
Last Update：2024-04-10 22:29:15
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