ALLYL CHLOROFORMATE (ACF)
Allyl chloroformate
CAS: 2937-50-0
Molecular Formula: C4H5ClO2
ALLYL CHLOROFORMATE (ACF) - Names and Identifiers
| Name | Allyl chloroformate |
| Synonyms | Allyl chloroformate allyl chlorocarbonate ALLYLCHLOROFORMATE(ACF) Allyl carbonochloridate 2-propenylchloroformate ALLYL CHLOROFORMATE (ACF) Prop-1-enylchlorocarbonate Chloridocarbonic acid allyl (Allyloxycarbonyl) chloride prop-2-en-1-yl carbonochloridate Chloridocarbonic acid allyl ester Alloc-Cl allyloxycarbonylchloride Carbonochloridic acid, 2-propenyl ester 4-amino-1-(beta-D-arabinofuranosyl)-5-fluoropyrimidin-2(1H)-one |
| CAS | 2937-50-0 |
| EINECS | 220-916-6 |
| InChI | InChI=1/C9H12FN3O5/c10-3-1-13(9(17)12-7(3)11)8-6(16)5(15)4(2-14)18-8/h1,4-6,8,14-16H,2H2,(H2,11,12,17)/t4-,5-,6+,8-/m1/s1 |
ALLYL CHLOROFORMATE (ACF) - Physico-chemical Properties
| Molecular Formula | C4H5ClO2 |
| Molar Mass | 120.53 |
| Density | 1.134g/mLat 20°C(lit.) |
| Melting Point | 106℃ |
| Boling Point | 109 °C |
| Flash Point | 88°F |
| Water Solubility | insoluble |
| Solubility | Chloroform |
| Vapor Presure | 3.67 psi ( 20 °C) |
| Appearance | Liquid |
| Color | Clear slightly yellow to light orange to reddish brown |
| Odor | Extremely irritating, causes tears; pungent. |
| BRN | 773915 |
| Storage Condition | 2-8°C |
| Stability | Moisture Sensitive |
| Refractive Index | n20/D 1.422(lit.) |
| Physical and Chemical Properties | Melting point 106 ℃ flash point 31.1 ℃ solubility soluble in benzene, ether, insoluble in water. |
| Use | Used as a reagent for organic synthesis |
ALLYL CHLOROFORMATE (ACF) - Risk and Safety
| Hazard Symbols | T+ - Very toxic |
| Risk Codes | R10 - Flammable R22 - Harmful if swallowed R26 - Very Toxic by inhalation R34 - Causes burns |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of soap-suds. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 1722 6.1/PG 1 |
| WGK Germany | 3 |
| RTECS | LQ5775000 |
| FLUKA BRAND F CODES | 19 |
| HS Code | 29159000 |
| Hazard Class | 6.1(b) |
| Packing Group | I |
ALLYL CHLOROFORMATE (ACF) - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| Uses | Allyl chloroformate is used to synthesize poly (ethylene oxide) hybrid systems for therapeutic applications and drug delivery. It is also used to synthesize benzothiazole derivatives with effective antitumor properties. Used as organic synthesis reagent |
| category | corroded articles |
| toxicity classification | poisoning |
| acute toxicity | oral-rat LD50: 244 mg/kg; Oral-mouse LD50: 210 mg/kg |
| flammability hazard characteristics | flammability |
| storage and transportation characteristics | warehouse ventilation and low temperature drying; separate from oxidant |
| fire extinguishing agent | sand, foam, carbon dioxide |
| occupational standard | STEL 0.4 mg/m3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 02:00:05
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