Name | Barium tetraoxomolybdate |
Synonyms | Barium molybdate BARIUM MOLYBDATE BARIUM MOLYBDATE OXIDE BARIUM MOLYBDENUM OXIDE Barium tetraoxomolybdate barium dioxido(dioxo)molybdenum |
CAS | 7787-37-3 |
EINECS | 232-111-7 |
InChI | InChI=1/Ba.Mo.4O/q+2;;;;2*-1/rBa.MoO4/c;2-1(3,4)5/q+2;-2 |
Molecular Formula | BaMoO4 |
Molar Mass | 297.27 |
Density | 4.65g/mLat 25°C(lit.) |
Melting Point | 1600°CC |
Water Solubility | Slightly soluble in water and acids |
Appearance | White powder |
Specific Gravity | 4.98 |
Color | White |
Exposure Limit | ACGIH: TWA 0.5 mg/m3NIOSH: IDLH 1000 mg/m3; IDLH 50 mg/m3; TWA 0.5 mg/m3 |
Solubility Product Constant(Ksp) | pKsp: 7.45 |
Storage Condition | Room Temprature |
MDL | MFCD00014182 |
Physical and Chemical Properties | Character white or light green powder or lumps. melting point 1480 ℃ relative density 4.65 solubility insoluble in water, slightly soluble in acids. |
Use | For the refinement of naphtha and the adhesion of enamel products |
Hazard Symbols | Xn - Harmful |
Risk Codes | 20/22 - Harmful by inhalation and if swallowed. |
Safety Description | 28 - After contact with skin, wash immediately with plenty of soap-suds. |
UN IDs | UN 1564 6.1/PG 3 |
WGK Germany | 1 |
TSCA | Yes |
Hazard Class | 6.1 |
Packing Group | III |
Raw Materials | Sodium carbonate Barium chloride Hydrochloric acid |
white or light green powder or cake. Relative density 4. 65. Melting point 1480 °c. Insoluble in water, slightly soluble in acids. Good adhesion to metals. Toxic!
double decomposition method: molybdenum concentrate is oxidized and roasted, and sodium molybdate solution is obtained by liquid alkali leaching. Under stirring, barium chloride solution is added to react to form barium molybdate precipitate, after drying, the barium molybdate product is obtained.
used as an adhesive for enamel products to make the enamel and iron adhere firmly. It can also be used to remove sulfur from naphtha.
packed with fiber barrels lined with clean polyethylene plastic bags. 40kg net weight per barrel. Care should be taken to prevent cracks in the mouth of the plastic bag. The package should be marked with "drug. Store in a ventilated and dry warehouse. In case of humid air, the powder is easy to absorb moisture and must be sieved. Tie the mouth of the bag tightly or cover tightly to avoid adhesion. It is not allowed to be stored and mixed with edible articles. Transport should be protected from rain and sun exposure. When loading and unloading should be light to prevent packaging damage. In case of fire, it can be suppressed by water, sand and all kinds of fire extinguishing. Toxicity and protection see Molybdenum trioxide.
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
solubility in water (g/100ml) | grams dissolved per 100ml of water: 6 × 10-3/20 ℃ |
toxicity | see Molybdenum trioxide. |
Use | used for refining naphtha and adhesion of enamel products used as an adhesive for enamel products, make the enamel and iron adhere firmly. It can also be used to remove sulfur from naphtha. |
production method | molybdenum concentrate by double decomposition method after oxidation roasting, sodium molybdate solution is obtained by liquid alkali leaching, barium chloride solution was added to react to generate barium molybdate precipitate. The precipitate was centrifuged, washed with water and dried to obtain barium molybdate finished product. 2MOS2 7O2 → 2MoO3 4SO2 moomoo3 2NaOH → Na2MoO4 H2ONa2MoO4 BaC12 → BaMo4 ↓ 2NaCl |