Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate
CAS: 178397-71-2
Molecular Formula: C15H16F3O3RhS
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate - Names and Identifiers
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate - Physico-chemical Properties
| Molecular Formula | C15H16F3O3RhS |
| Melting Point | 119-121 °C |
| Storage Condition | -20°C |
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves. |
| WGK Germany | 3 |
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate - Introduction
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate is an organometallic compound having the chemical formula [Rh(C7H8)2](CF3SO3), which may also be abbreviated as [BnR]OTf. The following is a description of its nature, use, formulation and safety information:
Nature:
-Appearance: colorless crystal
-Melting point: about 100°C
-Density: about 1.46 g/mL
-Solubility: Soluble in organic solvents such as ether and chloroform
Use:
-Catalyst: Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate are often used as catalysts and play an important role in organic synthesis reactions. It can catalyze alkene carbonylation, C- H activation, asymmetric synthesis and other reactions.
-Metal organic chemistry: Due to its metal organic properties, it can also be used in the research of organometallic chemistry.
Preparation Method:
Bis(norbornadiene) The preparation method of rhodium(I) trifluoromethanesulfonate is mainly by reacting RhCl(PPh3)3 with norbornadiene in a suitable solvent, and then adding trifluoromethanesulfonic acid.
Safety Information:
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate have certain toxicity, so appropriate safety measures need to be taken when using or handling. Avoid inhalation of dust, contact with skin and eyes. The working environment should be well ventilated.
Nature:
-Appearance: colorless crystal
-Melting point: about 100°C
-Density: about 1.46 g/mL
-Solubility: Soluble in organic solvents such as ether and chloroform
Use:
-Catalyst: Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate are often used as catalysts and play an important role in organic synthesis reactions. It can catalyze alkene carbonylation, C- H activation, asymmetric synthesis and other reactions.
-Metal organic chemistry: Due to its metal organic properties, it can also be used in the research of organometallic chemistry.
Preparation Method:
Bis(norbornadiene) The preparation method of rhodium(I) trifluoromethanesulfonate is mainly by reacting RhCl(PPh3)3 with norbornadiene in a suitable solvent, and then adding trifluoromethanesulfonic acid.
Safety Information:
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate have certain toxicity, so appropriate safety measures need to be taken when using or handling. Avoid inhalation of dust, contact with skin and eyes. The working environment should be well ventilated.
Last Update：2024-04-10 22:29:15
