Name | 6-Bromo-2-naphthol |
Synonyms | AI3-18464 NSC 17563 bromo-6naphtol-2 6-bromo-2-naphtho Bromo-6 naphtol-2 6-BROMO-2-NAPHTHOL 6-Bromo-2-naphthol 2-Naphthol, 6-bromo- 6-bromo-2-naphthaleno 6-Bromo-beta-naphthol 6-bromonaphthalen-2-ol 6-BROMO-2-NAPHTHALENOL 2-Naphthalenol, 6-bromo- Bromo-6 naphtol-2 [French] 2-Naphthalenol, 6-bromo- (9CI) |
CAS | 15231-91-1 |
EINECS | 239-279-0 |
InChI | InChI=1/C10H7BrO/c11-9-3-1-8-6-10(12)4-2-7(8)5-9/h1-6,12H |
Molecular Formula | C10H7BrO |
Molar Mass | 223.07 |
Density | 1.4412 (rough estimate) |
Melting Point | 122-124 °C (lit.) |
Boling Point | 130°C (rough estimate) |
Flash Point | 167.8°C |
Water Solubility | 不溶于水,溶于醇。 |
Solubility | Chloroform, Methanol |
Vapor Presure | 1.71E-05mmHg at 25°C |
Appearance | Slightly beige powder |
Color | Off-white to beige |
BRN | 1100270 |
pKa | 9.26±0.40(Predicted) |
Storage Condition | Inert atmosphere,Room Temperature |
Refractive Index | 1.5700 (estimate) |
MDL | MFCD00004081 |
Physical and Chemical Properties | White needle crystal. Melting point 127-128 ℃, boiling point 200-205 ℃(0.267kPa), soluble in benzene and ethanol. |
Use | Pharmaceutical Intermediates, liquid crystal raw materials. Organic synthesis and fuel intermediates, also used as insecticidal and bactericidal machine of raw materials. |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection |
WGK Germany | 3 |
RTECS | QL3365000 |
HS Code | 29037990 |
Hazard Note | Irritant |
chemical properties | white needle crystal. Melting point 127-128 ℃, boiling point 200-205 ℃(0.267kPa), soluble in benzene and ethanol. |
use | dye intermediate. Organic synthetic raw materials. Pharmaceutical intermediates, liquid crystal raw materials. Organic synthesis and fuel intermediates are also used as raw materials for insecticidal and sterilizer. |
production method | is obtained by bromination and reduction of 2-naphthol. Add 2-naphthol and glacial acetic acid to the reaction pot, and then add the solution prepared by bromine and acetic acid. Add bromine, add water and heat to boiling, then cool to 100 ℃, add moss-like tin in batches, boil for 3 hours after adding, add to an appropriate amount of cold water under stirring to precipitate 6-bromo-2-naphthol, wash with water, filter, and dry at 100 ℃ to obtain crude products. The finished product is obtained by vacuum distillation and recrystallization. |
NIST chemical information | The information is: webbook.nist.gov provides (external link) |
EPA chemical information | The information is: offered by ofmpub.epa.gov (external link) |