Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III)
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III)
CAS: 35886-64-7
Molecular Formula: C11H17CoI2O
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) - Names and Identifiers
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) - Physico-chemical Properties
| Molecular Formula | C11H17CoI2O |
| Molar Mass | 478 |
| Storage Condition | under inert gas (nitrogen or Argon) at 2–8 °C |
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) - Introduction
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) is an organometallic compound with the formula [Co(C5(CH3)5)(CO)I2]. It is a red solid, soluble in organic solvents. The following describes the properties, uses, preparation methods and safety information of the compound:
Nature:
1. Appearance: red solid;
2. Melting point: about 230-240°C;
3. Solubility: Soluble in benzene and other organic solvents, insoluble in non-polar solvents.
Use:
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) is mainly used as a transition metal catalyst in organic synthesis. It can catalyze a variety of organic reactions, such as the oxidation of olefins, the carbonylation of carboxylic acids and alcohols, and the activation of C- H bonds. In addition, it is also widely used in the research field of organic synthesis.
Preparation Method:
The preparation of Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) is usually carried out by the following steps:
1. reacting pentamethylcyclopentadienyl lithium (CpLi) with cobalt iodide (CoI2) to generate pentamethylcyclopentadienyl cobalt compound [Co(C5(CH3)5)I2];
2. The above compound is reacted with carbon monoxide (CO) under appropriate conditions to produce Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III).
Safety Information:
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) currently has no specific usability and safety assessment report, so it needs to be handled with caution when using it. Because it is an organometallic compound, it is usually necessary to carry out the reaction under an inert gas atmosphere and take appropriate protective measures. At the same time, avoid contact with the skin and eyes, should be placed in a closed container. In case of direct contact or accidental ingestion, seek medical attention immediately.
Nature:
1. Appearance: red solid;
2. Melting point: about 230-240°C;
3. Solubility: Soluble in benzene and other organic solvents, insoluble in non-polar solvents.
Use:
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) is mainly used as a transition metal catalyst in organic synthesis. It can catalyze a variety of organic reactions, such as the oxidation of olefins, the carbonylation of carboxylic acids and alcohols, and the activation of C- H bonds. In addition, it is also widely used in the research field of organic synthesis.
Preparation Method:
The preparation of Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) is usually carried out by the following steps:
1. reacting pentamethylcyclopentadienyl lithium (CpLi) with cobalt iodide (CoI2) to generate pentamethylcyclopentadienyl cobalt compound [Co(C5(CH3)5)I2];
2. The above compound is reacted with carbon monoxide (CO) under appropriate conditions to produce Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III).
Safety Information:
Carbonyldiiodo(pentamethylcyclopentadienyl)cobalt(III) currently has no specific usability and safety assessment report, so it needs to be handled with caution when using it. Because it is an organometallic compound, it is usually necessary to carry out the reaction under an inert gas atmosphere and take appropriate protective measures. At the same time, avoid contact with the skin and eyes, should be placed in a closed container. In case of direct contact or accidental ingestion, seek medical attention immediately.
Last Update：2024-04-10 22:29:15
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