Cerium(3+) bis(trimethylsilyl)amide

Cerium(3+) bis(trimethylsilyl)amide - Names and Identifiers

Name	Cerium III tris(bis(trimethylsilylamide))
Synonyms	Ceriumtrisbistrimethylsilylamide Cerium(3+) bis(trimethylsilyl)amide HEXAMETHYLDISILAZANE CERIUM(III) SALT CERIUM III TRIS[BIS(METHYLSILYLAMIDE)] N,N-BIS(TRIMETHYLSILYLAMINE)CERIUM(III) CERIUM III TRIS(BIS(TRIMETHYLSILYLAMIDE)) Cerium III tris(bis(trimethylsilylamide)) TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) cerium(3+) tris(1,1,1,3,3,3-hexamethyldisilazan-2-ide)
CAS	41836-21-9
InChI	InChI=1/3C6H18NSi2.Ce/c31-8(2,3)7-9(4,5)6;/h31-6H3;/q3*-1;+3

Cerium(3+) bis(trimethylsilyl)amide - Physico-chemical Properties

Molecular Formula	C6H19CeNSi2
Molar Mass	301.51
Melting Point	132-140°C(lit.)
Boling Point	95-9°C/10-4mmHg
Flash Point	36°F
Water Solubility	Soluble in water, protic solvents.
Vapor Presure	11.9mmHg at 25°C
Appearance	Powder
Storage Condition	Flammables + water-Freezer (-20°C)e area
Sensitive	Moisture Sensitive
MDL	MFCD03411241

Cerium(3+) bis(trimethylsilyl)amide - Risk and Safety

Risk Codes	R11 - Highly Flammable R14/15 - R34 - Causes burns
Safety Description	S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S7/8 -
UN IDs	UN 3396 4.3/PG 2
WGK Germany	3
TSCA	No
Hazard Class	4.1
Packing Group	III

Cerium(3+) bis(trimethylsilyl)amide - Introduction

Cerium III tris(bis(trimethylsilylamide)) is a chemical compound with the formula Ce[N(SiMe3)2]3Cs. Its nature, use, formulation and safety information are described below:

Nature:
-Appearance: colorless crystal
-Solubility: Soluble in non-polar solvents (such as hydrocarbon solvents), insoluble in water
-Melting point: about 150-160°C
-Density: about 1.2g/cm³

Use:
- Cerium III tris(bis(trimethylsilylamide)) is widely used in chemical research, mainly as a coordinating reagent and catalyst.
-It can be used as an organometallic precursor to participate in organometallic chemical reactions, such as the synthesis of new coordination compounds or organometallic catalysts.
-This compound can also be used as a precursor for photoluminescent materials and phosphorescent materials.

Preparation Method:
Cerium III tris(bis(trimethylsilylamide)) can be synthesized:
1. The tris [N,N-bis(trimethylsilyl) amine] aluminum reacts with cesium chloride to generate the precursor of Cerium III tris(bis(trimethylsilylamide)).
2. The precursor is dissolved in a polar solvent, and under appropriate conditions (such as heating or vacuum conditions), Cerium III tris(bis(trimethylsilylamide)) is obtained by a de-ligand reaction.

Safety Information:
-The toxicity and danger of Cerium III tris(bis(trimethylsilylamide)) has not been fully evaluated. Therefore, in the contact and operation, should follow the laboratory safety procedures.
-It may be irritating to the human body, so personal protective equipment such as respirators, goggles and gloves are required.
-If inhaled, ingested, or in contact with skin, seek medical attention immediately and provide detailed compound information.
-When using or handling the compound, avoid reacting with strong oxidants or water to avoid possible dangerous accidents.

Last Update：2024-04-10 22:29:15