Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium - Names and Identifiers
Name | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
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Synonyms | Cp*RuCl(cod) 1,5-Cyclooctadiene, ruthenium complex Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
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CAS | 92390-26-6
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InChIKey | JBVMVFXUVNUNNG-ONEVTFJLSA-M |
Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium - Physico-chemical Properties
Molecular Formula | C18H27ClRu5*
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Molar Mass | 379.93 |
Melting Point | 143-147℃ |
Color | brown microxtls |
Storage Condition | -20°C |
Stability | store cold |
MDL | MFCD07369035 |
Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium - Risk and Safety
Hazard Symbols | F - Flammable
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Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R14/15 -
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Safety Description | S22 - Do not breathe dust.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
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UN IDs | UN 3395 |
WGK Germany | 3 |
TSCA | No |
Hazard Class | 4.3 |
Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium - Introduction
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a metal organic compound with the chemical formula C14H21ClRu and a molecular weight of 380.05g/mol.
Nature:
1. appearance: colorless to light yellow crystal.
2. melting point: about 165-167 ℃.
3. Solubility: Soluble in organic solvents such as dichloromethane, ether, slightly soluble in water.
4. Stability: Stable at room temperature, but may decompose when heated.
Use:
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is an important coordination compound, which has a wide range of applications in organic synthesis and catalytic reactions. It can be used as catalyst, reducing agent and catalyst precursor. It plays an important role in hydrogenation, hydrogenation, olefin cyclization and carbonylation reactions.
Preparation Method:
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) can be prepared by reacting pentamethylcyclopentadiene ruthenium(II) chloride with sodium cyclooctadiene. First, pentamethylcyclopentadiene ruthenium (II) chloride and sodium cyclooctadiene are reacted in an organic solvent, and then the reaction product is appropriately treated and purified to obtain the target compound.
Safety Information:
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) toxicity data are limited and lack of systematic evaluation. It is a chemical that requires compliance with relevant safety procedures when used. Avoid direct contact with skin and eyes during operation, and avoid inhaling dust or vapor. Pay attention to ventilation during use and wear appropriate personal protective equipment when required.
Please note that the above information is for informational purposes only and additional specialized literature and chemical databases may be required for specific properties, uses, methods and safety information.
Last Update:2024-04-10 22:29:15