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Diethylene glycol monomethyl ether

2-(2-Methoxyethoxy)Ethanol

CAS: 111-77-3

Molecular Formula: C5H12O3

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Diethylene glycol monomethyl ether - Names and Identifiers

Name 2-(2-Methoxyethoxy)Ethanol
Synonyms DEM
MECB
dowanol dm
hicotol car
methyl digol
ektasolve dm
Poly-Solv DM
Methyl Carbitol
methoxydiglycol
methyl dioxitol
glycol ether dm
3,6-Dioxaheptan-1-ol
methoxyethoxyethanol
3,6-dioxa-1-heptanol
METHYLDIETHYLENEGLYCOL
2-beta-methyl carbitol
2-(Methoxyethoxy)ethanol
diglycol monomethyl ether
2-(2-Methoxyethoxy)Ethanol
Diethylenglycolmonomethylether
Diethylene glycol methyl ether
1-(2-hydroxyethoxy)propan-2-ol
ethylene diglycol monomethyl ether
Diethylene Glycol Monomethyl Ether
2,2'-oxybisethanol monomethyl ether
beta-methoxy-beta'-hydroxydiethyl ether
2-(2-Methoxyethoxy)ethanol, Methyldiglycol
2-(2-Methoxyethoxy)ethanol, DOWANOL(R) DM, Methyldiglycol
2-(2-methoxyethoxy)ethanol diethylene glycol monomethyl ether
CAS 111-77-3
EINECS 203-906-6
InChI InChI=1/C5H12O3/c1-5(7)4-8-3-2-6/h5-7H,2-4H2,1H3
InChIKey SBASXUCJHJRPEV-UHFFFAOYSA-N

Diethylene glycol monomethyl ether - Physico-chemical Properties

Molecular FormulaC5H12O3
Molar Mass120.15
Density1.023g/mLat 25°C(lit.)
Melting Point−70°C(lit.)
Boling Point194°C(lit.)
Flash Point183°F
Water SolubilityMiscible
Vapor Presure0.2 mm Hg ( 20 °C)
Vapor Density4.14 (vs air)
AppearanceLiquid
ColorClear
OdorFaint pleasant odor
Merck14,6037
BRN1697812
pKa14.37±0.10(Predicted)
PH4-7 (200g/l, H2O, 20℃)
Storage ConditionStore below +30°C.
StabilityStable. Incompatible with strong oxidizing agents. Hygroscopic. Store under nitrogen.
SensitiveHygroscopic
Explosive Limit1.38-22.7%
Refractive Indexn20/D 1.426
MDLMFCD00002871
Physical and Chemical Properties

density 1.01
melting point -70°C
boiling point 194°C
refractive index 1.425-1.427
flash point 83°C
water-soluble Miscible

UseIt is used as a solvent for nitrocellulose, resin, wood coloring dye, ink, alcohol ether dye, and as an extractant, improver and intermediate.

Diethylene glycol monomethyl ether - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk Codes63 - Possible risk of harm to the unborn child
Safety Description36/37 - Wear suitable protective clothing and gloves.
WGK Germany1
RTECSKL6125000
TSCAYes
HS Code29094200
ToxicityLD50 orally in rats: 9.21 g/kg (Smyth)

Diethylene glycol monomethyl ether - Upstream Downstream Industry

Raw Materials1-Butanol
Ethylene Oxide
Methyl alcohol
Methyl alcohol
Ethyl Alcohol
Downstream ProductsBis(2-methoxy ethyl)ether

Diethylene glycol monomethyl ether - Introduction

It has an aromatic smell. It's hygroscopic. It can be miscible with water, ethanol, glycerin, ether, acetone, dimethylacetamide, etc. The median lethal dose (rat, oral) was 9.21 g/kg. It's irritating.
Last Update:2022-10-16 17:12:04

Diethylene glycol monomethyl ether - Reference Information

LogP-0.47 at 20℃
NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
use used as a high boiling point solvent for inks, dyes, resins, cellulose and coatings, and also used in organic synthesis. The oral LD50 of this product to mice is 9200mg/kg.
Used as a solvent for nitrocellulose, resin, wood coloring dyes, inks, alcohol ether dyes, etc.
Used as an extractant, improver, etc.
Used as a solvent and an intermediate for preparing ester derivatives
Used as a solvent for nitrocellulose, resin, wood coloring dyes, inks, alcohol ether dyes, and also used as an extractant, improver and intermediate
solvent. Organic synthesis intermediate.
Production method It is obtained by the reaction of ethylene glycol monomethyl ether and ethylene oxide.
category combustible items
toxicity classification low toxicity
acute toxicity oral-rat LD50: 5500 mg/kg; Oral-mouse LD50: 8222 mg/kg
stimulation data eye-rabbit 500 mg/24 hours mild
flammability hazard characteristics combustible in case of open flame, high temperature and strong oxidant; Combustion emission stimulates smoke
storage and transportation characteristics complete packaging, light loading and unloading; warehouse ventilation, away from open flames, high temperature, separate storage from oxidant
fire extinguishing agent foam, dry powder, carbon dioxide
spontaneous combustion temperature 221°C
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-09 21:04:16
Diethylene glycol monomethyl ether
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View History
Diethylene glycol monomethyl ether
2-乙基-2-异戊基-丙二酸二乙酯
4-乙氧基苯甲酸乙酯
Phosphoric Pentoxide
三(二甲胺基)乙基硅烷
Raw Materials for Diethylene glycol monomethyl ether
1-Butanol
Ethylene Oxide
Methyl alcohol
Methyl alcohol
Ethyl Alcohol
Downstream Products for Diethylene glycol monomethyl ether
Bis(2-methoxy ethyl)ether
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