Name | Ethanesulfonyl chloride |
Synonyms | ETHYLSULFONYL CHLORIDE Ethyl sulfone chloride ETHANESULFONYL CHLORIDE Ethanesulbonyl Chloride Ethanesulfonyl chloride ETHANESULPHONYL CHLORIDE ethanesulflonyl chloride 1-Ethanesulfonyl chloride |
CAS | 594-44-5 |
EINECS | 209-842-5 |
InChI | InChI=1/C2H5ClO2S/c1-2-6(3,4)5/h2H2,1H3 |
InChIKey | FRYHCSODNHYDPU-UHFFFAOYSA-N |
Molecular Formula | C2H5ClO2S |
Molar Mass | 128.58 |
Density | 1.357 g/mL at 25 °C (lit.) |
Melting Point | -70°C |
Boling Point | 177 °C (lit.) |
Flash Point | 182°F |
Water Solubility | DECOMPOSES |
Solubility | soluble in dichloromethane,Ether |
Vapor Presure | 1.9mmHg at 25°C |
Appearance | Liquid |
Color | Clear colorless to light yellow or light brownish to pinkish-purple |
BRN | 773865 |
Storage Condition | Inert atmosphere,2-8°C |
Sensitive | Moisture Sensitive |
Refractive Index | n20/D 1.452(lit.) |
MDL | MFCD00007460 |
Physical and Chemical Properties | Light yellow liquid. Boiling point 171 ℃(177.5 ℃),90-92 ℃(7.33kPa),65 ℃(1.73kPa), relative density 1.357(22.5 ℃), refractive index 1.4531. Soluble in ether, soluble in methylene chloride. Water and ethanol decomposition. |
Use | Used as pharmaceutical, pesticide intermediates |
Hazard Symbols | T - Toxic |
Risk Codes | R21/22 - Harmful in contact with skin and if swallowed. R23 - Toxic by inhalation R34 - Causes burns R22 - Harmful if swallowed |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 2927 6.1/PG 2 |
WGK Germany | 3 |
RTECS | KI8050000 |
FLUKA BRAND F CODES | 19-21 |
TSCA | Yes |
HS Code | 29049090 |
Hazard Class | 6.1 |
Packing Group | II |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Use | for organic synthesis. used as pharmaceutical and pesticide intermediates |
production method | is obtained by reacting ethyl thiocyanate with chlorine. 200g of ethyl thiocyanate was suspended in 200ml of water, and chlorine gas was introduced under vigorous stirring at 0-5 °c until the reaction solution appeared persistent yellow. Then the chlorine gas was driven out by compressed air, the oil layer was separated, extracted with ether, and washed with sodium disulfide and sodium carbonate successively. After drying with calcium chloride and fractional distillation under reduced pressure, fractions of 71-72 °c (2.67kPa) were collected to obtain about 230g of the product. The yield was about 79%. |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |