Hafnium, Tetrakis(diethylamino)

Hafnium, Tetrakis(diethylamino) - Names and Identifiers

Name	Tetrakis(diethylamino)hafnium(IV)
Synonyms	HAFNIUM DIETHYLAMIDE TETRAKIS(DIETHYLAMINO)HAFNIUM Hafnium, Tetrakis(diethylamino) tetrakis(diethylamino)hafnium(iv) tetrakis(diethylamido)hafnium(iv) Tetrakis(diethylamino)hafnium(IV)
CAS	19824-55-6

Hafnium, Tetrakis(diethylamino) - Physico-chemical Properties

Molecular Formula	C16H40HfN4
Molar Mass	467.01
Density	1.249g/mLat 25°C(lit.)
Melting Point	-68 °C
Boling Point	130°C0.01mm Hg(lit.)
Flash Point	50°F
Appearance	liquid
Specific Gravity	1.249
Color	light yellow
Sensitive	8: reacts rapidly with moisture, water, protic solvents

Hafnium, Tetrakis(diethylamino) - Risk and Safety

Risk Codes	R11 - Highly Flammable R14 - Reacts violently with water R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing.
UN IDs	UN 3398 4.3/PG 2
WGK Germany	3
TSCA	No
Hazard Class	4.3
Packing Group	II

Hafnium, Tetrakis(diethylamino) - Introduction

Tetrakis(diethylamino)hafnium(IV), of the formula Hf(N(C2H5)2)4, is an organic hafnium compound. The compound is in the form of a yellow powder and is soluble in non-polar solvents such as benzene and carbon disulfide.

Tetrakis(diethylamino)hafnium(IV) can be used as catalysts in certain chemical reactions, especially in hydrogenation reactions and carbon-hydrogen bond activation reactions in organic synthesis. It can also be used as a pre-denitrification agent to remove nitrogen contaminants.

Preparation of Tetrakis(diethylamino)hafnium(IV) can be obtained by reacting diethylamine with hafnium chloride under N2 atmosphere. The reaction is usually carried out under an inert atmosphere to avoid the influence of air and moisture.

When using this compound, necessary safety measures need to be taken. Tetrakis(diethylamino)hafnium(IV) is irritating to the skin and eyes and may cause allergic reactions. Therefore, avoid contact with skin and eyes during handling and storage, and take appropriate protective measures, such as wearing gloves and goggles. At the same time, it should be operated in a well-ventilated place, away from fire and sparks.

Last Update：2024-04-10 22:29:15