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Manganese oxide (Mn2O3)

Manganese(III) oxide

CAS: 1317-34-6

Molecular Formula: Mn2O3

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Manganese oxide (Mn2O3) - Names and Identifiers

Name Manganese(III) oxide
Synonyms Manganic oxide
Manganese trioxide
Manganese(3+) oxide
Manganese manganate
Dimanganese trioxide
Manganese(III) oxide
Manganese sisquioxide
Manganese sesquioxide
Manganese oxide (Mn2O3)
dimanganic oxygen(-2) anion
oxo(oxomanganiooxy)manganese
oxo-(oxomanganiooxy)manganese
keto(ketomanganiooxy)manganese
CAS 1317-34-6
EINECS 215-264-4
InChI InChI=1/2Mn.3O/q2*+3;3*-2
InChIKey GEYXPJBPASPPLI-UHFFFAOYSA-N

Manganese oxide (Mn2O3) - Physico-chemical Properties

Molecular FormulaMn2O3
Molar Mass157.87
Density4.5g/mLat 25°C(lit.)
Melting Point1080°C (dec.)
Water SolubilitySoluble in acid and ammonium chloride. Insoluble in water, alcohol and acetone.
AppearancePowder
Specific Gravity4.5
ColorBlack
Exposure LimitACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Merck14,5737
Storage ConditionRoom Temprature
MDLMFCD00016217
UseIs the raw materials and intermediate products of manganese compounds

Manganese oxide (Mn2O3) - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
WGK Germany3
RTECSOP0915000
TSCAYes

Manganese oxide (Mn2O3) - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Physical and chemical properties Manganese trioxide is a black cubic crystal, insoluble in water, acetic acid and ammonium chloride solutions, and soluble in other inorganic acids.
heating to 1080 ℃ to decompose to generate Mn3O4 and O2. Dissolve in cold hydrochloric acid into a brown solution, in hot dilute sulfuric acid or concentrated sulfuric acid into a red solution, in hot nitric acid decomposition into MnO2 and manganese nitrate, heat decomposition into Mn3O4 and release O2. It exists in the form of α-Mn2O3 and γ-Mn2O3.
preparation method α-type can be produced by heating the nitrate, carbonate or chloride, and hydride of divalent manganese in the air to 600~800 ℃ Decomposition. The γ-type can be prepared by heating MnO2 at 500 ℃ in vacuum for 78 hours, or by dehydrating γ-MnO(OH).
Application The hydrated oxide of manganese trioxide for trivalent manganese is called manganese brown, which is used as an printing agent for cloth, and it is also a raw material for making manganese compounds And intermediate products.
store manganese trioxide is packed in inert gas plastic bags, sealed and stored in a dry and cool environment, and should not be exposed to the air to prevent oxidation and agglomeration due to moisture, thus affecting the dispersion performance and use effect.
use is the raw material and intermediate product of manganese compounds
category toxic substances
toxicity classification poisoning
acute toxicity subcutaneous-mouse LD50: 616 mg/kg
flammability hazard characteristics non-combustible; toxic manganese smoke from the fire site
storage and transportation characteristics warehouse low temperature, ventilation, drying
fire extinguishing agent water, carbon dioxide, dry powder, sand
occupational standard TWA 5 mg (manganese)/m3
Last Update:2024-04-10 22:29:15
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Manganese oxide (Mn2O3)
(2S,5R)-苄氧胺基哌啶-2-甲酰胺
5-((1S)-1-AMINOETHYL)-2-METHYLPHENYLAMINE DIHYDROCHLORIDE
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