Methylcyclopentadienyl manganese tricarbonyl
tricarbonyl(methylcyclopentadienyl)manganese
CAS: 12108-13-3
Molecular Formula: C9H7MnO35*
Methylcyclopentadienyl manganese tricarbonyl - Names and Identifiers
Methylcyclopentadienyl manganese tricarbonyl - Physico-chemical Properties
| Molecular Formula | C9H7MnO35* |
| Molar Mass | 218.09 |
| Density | 1.38 g/mL at 25 °C (lit.) |
| Melting Point | -1 °C (lit.) |
| Boling Point | 232-233 °C (lit.) |
| Flash Point | 205°F |
| Water Solubility | Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone |
| Vapor Presure | 0.05 mm Hg ( 20 °C) |
| Vapor Density | >1 (vs air) |
| Appearance | liquid |
| Specific Gravity | 1.388 |
| Color | yellow |
| Exposure Limit | ACGIH: TWA 0.2 mg/m3 (Skin)OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 0.2 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3 |
| Merck | 14,6223 |
| Storage Condition | Poison room |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| Sensitive | Air Sensitive |
| Refractive Index | n20/D 1.584(lit.) |
| Physical and Chemical Properties | |
| Use | Gasoline anti-Storm agent gasoline target agent unleaded gasoline anti-knock agent gasoline octane number improver |
Methylcyclopentadienyl manganese tricarbonyl - Risk and Safety
| Risk Codes | R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R40 - Limited evidence of a carcinogenic effect R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R48/23 - R38 - Irritating to the skin R26 - Very Toxic by inhalation R24/25 - |
| Safety Description | S23 - Do not breathe vapour. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S60 - This material and its container must be disposed of as hazardous waste. S36/37 - Wear suitable protective clothing and gloves. S28 - After contact with skin, wash immediately with plenty of soap-suds. |
| UN IDs | UN 3281 6.1/PG 2 |
| WGK Germany | 3 |
| RTECS | OP1450000 |
| TSCA | Yes |
| Hazard Class | 6.1 |
| Packing Group | II |
| Toxicity | LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara) |
Methylcyclopentadienyl manganese tricarbonyl - Reference Information
| LogP | 3.4 at 26℃ |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | gasoline anti-Storm agent gasoline target agent unleaded gasoline anti-knock agent gasoline octane number improver target agent symplectic agent |
| category | toxic substances |
| toxicity grade | highly toxic |
| Acute toxicity | oral-rat LD50: 8 mg/kg; Oral-mouse LD50: 34 mg/kg |
| stimulation data | Skin-rabbits 100 mg/24 h mild |
| flammability hazard characteristics | flammable; Fire decomposition toxic manganese oxide smoke |
| storage and transportation characteristics | The warehouse is low temperature, ventilated and dry, and stored separately from food raw materials |
| extinguishing agent | water, carbon dioxide, foam, dry powder |
| Occupational Standard | TWA 0.2 mg/m3; Tel 0.6 mg/m3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-10 22:29:15
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