NIR-C 1

NIR-C 1 - Names and Identifiers

Name	tetrabutylammonium bis(4-methyl-1,2-benzenedithio
Synonyms	NIR-C 1 nickelate tetrabutylammonium TETRABUTYLAMMONIUM BIS(4-METHYL-1 2- tetrabutylammonium bis(4-methyl-1,2-benzenedithio Tetrabutylammonium bis(4-methyl-1,2-benzenedithiolato) Tetrabutylammonium bis(4-methyl-1,2-benzenedithiolato)nickelate Tetrabutylammonium Bis(4-methyl-1,2-benzenedithiolato)nickel(III) Complex (4-methyl-2-sulfido-phenyl)sulfanyl-(5-methyl-2-sulfido-phenyl)sulfanyl-nickel
CAS	15492-42-9
InChI	InChI=1/C16H36N.2C7H8S2.Ni/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;21-5-2-3-6(8)7(9)4-5;/h5-16H2,1-4H3;22-4,8-9H,1H3;/q+1;;;+3/p-4/rC16H36N.C14H14NiS4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-9-4-6-13(12(17)7-9)18-15-19-14-8-10(2)3-5-11(14)16/h5-16H2,1-4H3;3-8,16-17H,1-2H3/q2*+1/p-2

NIR-C 1 - Physico-chemical Properties

Molecular Formula	C16H36N.C14H12NiS4
Molar Mass	609.673
Melting Point	149-151°C(lit.)
Appearance	powder to crystal
Color	Dark green to Dark red to Black
Storage Condition	under inert gas (nitrogen or Argon) at 2-8°C

NIR-C 1 - Risk and Safety

Hazard Symbols	Xn - Harmful
Risk Codes	R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing.
WGK Germany	3
HS Code	29420000

NIR-C 1 - Introduction

tetrabutylammonium bis(4-methyl-1,2-benzenedithio is an organometallic compound with the chemical formula (Ni(DBDT-Se)2(Bu)4), which can also be abbreviated as Ni(DBDT-Se)2.

Nature:
-Appearance: Tetrabuutylammonium bis(4-methyl-1,2-benzenedithio is an orange-red crystalline powder solid.
-Melting point: About 272-274 degrees Celsius.
-Solubility: Soluble in organic solvents such as dimethylformamide (DMF) and dichloromethane.

Use:
-Catalyst: Tetrabuutylammonium bis(4-methyl-1,2-benzenedithio can be used as a catalyst, which is often used in hydrogenation, Carbonylation and reduction reactions in organic synthesis.
-Electrochemical materials: Due to the metal nickel ion in the complex, it has potential in the field of electrochemical energy storage and catalysis.

Method:
The preparation of tetrabuutylammonium bis(4-methyl-1,2-benzenedithio can be completed through chemical reactions during the synthesis. This process is generally through the reaction of tetrabutylammonium and methyl benzene disulfide, and the addition of an appropriate amount of nickel sulfide, which is coordinated with methyl benzene disulfide to form a complex.

Safety Information:
Specific security information for tetrabuutylammonium bis(4-methyl-1,2-benzenedithio has not been provided. When handling and using, it is recommended to follow regular laboratory safety procedures and avoid direct contact with skin and eyes.

Last Update：2024-04-10 22:29:15