PICRIC ACID, SATURATED
Picric acid
CAS: 88-89-1
Molecular Formula: C6H3N3O7
PICRIC ACID, SATURATED - Names and Identifiers
| Name | Picric acid |
| Synonyms | C.I. 10305 Picric acid PICRIC ACID PICRINIC ACID PICRONITRIC ACID PHENOL TRINITRATE 2,4,6-Trinitrophenol PICRIC ACID, SATURATED |
| CAS | 88-89-1 |
| EINECS | 201-865-9 |
| InChI | InChI=1/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H |
| InChIKey | OXNIZHLAWKMVMX-UHFFFAOYSA-N |
PICRIC ACID, SATURATED - Physico-chemical Properties
| Molecular Formula | C6H3N3O7 |
| Molar Mass | 229.1 |
| Density | 1.00g/mLat 20°C |
| Melting Point | 122-123°C (dried material, Lit. Merck Index 12th Ed.)(lit.) |
| Boling Point | 300℃ |
| Flash Point | 150℃ |
| Water Solubility | (mg/L):66,670 at 100 °C (quoted, Windholz et al., 1983)14,000 at 20 °C, 68,000 at 100 °C (quoted, Verschueren, 1983) |
| Solubility | alcohol: soluble1 (g/12 mL)(lit.) |
| Vapor Presure | 1 mm Hg ( 195 °C) |
| Vapor Density | 7.9 (vs air) |
| Appearance | solution (saturated aqueous) |
| Specific Gravity | 1.005 |
| Color | yellow solution |
| Exposure Limit | TLV-TWA skin 0.1 mg/m3 (ACGIH, OSHA, and MSHA). |
| Maximum wavelength(λmax) | ['354nm'] |
| Merck | 13,7492 |
| BRN | 423400 |
| pKa | 0.38(at 25℃) |
| Storage Condition | Store at RT. |
| Stability | Stability Unstable; may detonate if struck, heated or ground. Highly flammable if dry. May explode if dry - keep wet at all times. Keep water content above 20%. Flammable. Incompatible with strong oxi |
| Explosive Limit | 0.01% |
| Refractive Index | 1.7630 (estimate) |
| Physical and Chemical Properties | Characteristic yellow crystals. The taste is very bitter, not easy to absorb moisture. melting point 122~123 ℃ boiling point 300 ℃ relative density 1.763g/cm3 flash point 150 ℃ solubility insoluble in cold water, soluble in hot water, soluble in ethanol, ether, benzene and chloroform. |
| Use | For the production of red sulfide black and acid dyes, photographic drugs, explosives and pesticides, medicine used as a surgical astringent |
PICRIC ACID, SATURATED - Risk and Safety
| Risk Codes | R1 - Explosive when dry R4 - Forms very sensitive explosive metallic compounds R11 - Highly Flammable R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R2 - Risk of explosion by shock, friction, fire or other sources of ignition R36 - Irritating to the eyes R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R3 - Extreme risk of explosion by shock, friction, fire or other sources of ignition |
| Safety Description | S35 - This material and its container must be disposed of in a safe way. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S37 - Wear suitable gloves. S28 - After contact with skin, wash immediately with plenty of soap-suds. S36/37 - Wear suitable protective clothing and gloves. S36 - Wear suitable protective clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S16 - Keep away from sources of ignition. S25 - Avoid contact with eyes. |
| UN IDs | UN 1344 4.1/PG 1 |
| WGK Germany | 2 |
| RTECS | TJ7875000 |
| Hazard Class | 4.1 |
| Packing Group | I |
| Toxicity | LC50 (48-h) for red killifish 513 mg/L (Yoshioka et al., 1986). |
PICRIC ACID, SATURATED - Upstream Downstream Industry
PICRIC ACID, SATURATED - Nature
Open Data Verified Data
white or light yellow needle-like crystals. Bitter, not easy to absorb moisture. Insoluble in cold water, soluble in hot water, soluble in benzene, hot chloroform and boiling alcohol, slightly soluble in ether and gasoline. It is prone to explosion when dry. It is a strong oxidant, and can react with combustible materials and reducing agents to cause combustion and explosion. Can corrode metals, and the resulting metal salts are extremely sensitive to shock or heat. When heated, exposed to open flame, high heat, or subjected to friction and shock, explosion can occur. Reactions with strong oxidants may occur. It can react with heavy metal powder to form metal salt, which increases sensitivity.
Last Update：2024-01-02 23:10:35
PICRIC ACID, SATURATED - Preparation Method
Open Data Verified Data
A mixture of 2,4-= nitrochlorobenzene and 2,6-= nitrochlorobenzene was hydrolyzed with sodium hydroxide to give 2,4-= nitrophenol sodium and 2, A mixture of 6-nitrophenol sodium was acidified with sulfuric acid and then nitrated with a mixed acid of concentrated sulfuric acid and nitric acid. The product was suction-filtered and washed with water to obtain sodium dinitrophenolate.
Last Update：2022-01-01 10:06:56
PICRIC ACID, SATURATED - Use
Open Data Verified Data
This product is used as a polymerization inhibitor. This product is an intermediate for the preparation of red sulfide black and acid dyes, photographic drugs, explosives and pesticides such as chloropicrin. Used medically as a surgical astringent. It is commonly used for the isolation and purification of organic bases.
Last Update：2022-01-01 10:06:57
PICRIC ACID, SATURATED - Safety
Open Data Verified Data
toxic. Mice were injected intraperitoneally with LD50: 56.3 mg/kg. It is very irritating, can cause skin damage, make the skin yellow, cause contact dermatitis, conjunctivitis and bronchitis. Keep away from fire and heat source. Should be stored separately from the alkali, oxidant, starting equipment, etc.
Last Update：2022-01-01 10:06:57
PICRIC ACID, SATURATED - Reference Information
| Color index | 10305 |
| pH range of acid-base indicator discoloration | 0.2(colourless)-1(yellow) |
| Main applications | expansions, power circuits, energetic materials, liquemedgas fuels, thin films, power generation, batteries, fuel cells, steel, gold films, nanopowder, anti-freeze fluid for automobiles, polymerization inhibitors, tattoo removal from skin, antiinfiammatroy agent, treatment of neoplasm |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Coagulation fixative | picric acid penetrates slowly into the tissue, and can strongly contract the tissue. But can make protein. The nucleic acid and the like are precipitated, and excessive hardening is prevented, and the ability to improve the dyeing ability in the future is great. Usually rarely used alone, often mixed with other drugs. After fixation need to be washed with 50% or 70% alcohol. Features: weak penetration, easy to make the tissue contraction, easy to explosion. Note: generally washed with 50% or 70% alcohol. |
| Use | used in the manufacture of red sulfide black and acid dyes, photographic drugs, explosives and pesticides, medically used as a surgical astringent as an analytical reagent |
| category | explosive articles |
| toxicity grade | high toxicity |
| Acute toxicity | oral-rat LD50: 200 mg/kg; Abdominal injection-mouse LD50: 56.3 mg/kg |
| explosive hazard characteristics | high heat, vibration, impact, and friction burst |
| flammability hazard characteristics | toxic NOx smoke from combustion |
| storage and transportation characteristics | light weight; Warehouse ventilation, away from open flame, high temperature, sunlight; And oxidant, separate storage of combustible materials |
| extinguishing agent | Water |
| Occupational Standard | TLV-TWA 0.1 mg/m3; Tel 0.3 mg/m3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
| immediate life-and health-threatening concentration | 75 mg/m3 |
Last Update：2024-04-09 19:05:15
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CAS: 88-89-1
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Mobile: 0086 189 4982 3763
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View History
PICRIC ACID, SATURATED
4-PHENYLOXY-2,6-DIISOPROPYLANILINE
LITHIUM ORTHOPHOSPHATE
Hexamethylphosphoric triamide Solution
盐酸克林霉素棕榈酯 USP标准品
2-氧代-2-(3-吡啶基)乙酸3-吡啶基乙醛酸
4-PHENYLOXY-2,6-DIISOPROPYLANILINE
LITHIUM ORTHOPHOSPHATE
Hexamethylphosphoric triamide Solution
盐酸克林霉素棕榈酯 USP标准品
2-氧代-2-(3-吡啶基)乙酸3-吡啶基乙醛酸
Raw Materials for PICRIC ACID, SATURATED