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Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)-

phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

CAS: 162881-26-7

Molecular Formula: C26H27O3P

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Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)- - Names and Identifiers

Name phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Synonyms OMNIRAD 380
OMNIRAD 819
Photoinitiator 819
Photoinitiator-819
former IRGACURE 819
(Phenylphosphoryl)bis(mesitylmethanone)
Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide
PHENYLBIS(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE
phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Phosphine oxide, phenylbis(2,4,6-trimethylbenzoyl)-
Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)-
(phenylphosphoryl)bis[(2,4,6-trimethylphenyl)methanone]
CAS 162881-26-7
EINECS 423-340-5
InChI InChI=1/C26H27O3P/c1-16-12-18(3)23(19(4)13-16)25(27)30(29,22-10-8-7-9-11-22)26(28)24-20(5)14-17(2)15-21(24)6/h7-15H,1-6H3
InChIKey GUCYFKSBFREPBC-UHFFFAOYSA-N

Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)- - Physico-chemical Properties

Molecular FormulaC26H27O3P
Molar Mass418.47
Density1.17±0.1 g/cm3(Predicted)
Melting Point131-135°C(lit.)
Boling Point590.0±60.0 °C(Predicted)
Flash Point310.6°C
Water Solubility100μg/L at 20-21℃
Solubility acetone, acetonitrile, toluene, and hexanedioldiacrylate: soluble
Vapor Presure0Pa at 20℃
Appearancepowder
ColorPale Yellow to Yellow
Maximum wavelength(λmax)['366nm(MeOH)(lit.)']
Storage ConditionSealed in dry,Room Temperature
Refractive Index1.588
Physical and Chemical PropertiesAppearance: light yellow powder
Melting Point: 131-135°C
flash point: 310.6°C
Boiling Point: 90°C (760 mmHg)
density: 1.17g/cm3

Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)- - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk CodesR43 - May cause sensitization by skin contact
R53 - May cause long-term adverse effects in the aquatic environment
Safety DescriptionS22 - Do not breathe dust.
S24 - Avoid contact with skin.
S37 - Wear suitable gloves.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
WGK Germany-
HS Code29319090

Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)- - Reference Information

LogP5.77-5.8 at 22℃
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
application photoinitiator 819 can also be used for colored UV curing plastic coatings. UV coatings have been widely used on plastic shells of various electronic and home appliance products due to their excellent performance and efficient production. however, the UV coating film does not cure well after adding color, resulting in poor adhesion of the coating film, as well as the poor dispersion and arrangement of pigments by UV resin, it seriously affects the appearance of the coating film. Therefore, the traditional construction process is to first coat solvent-based colored primer for coloring, and then coat UV varnish after baking to improve the various physical properties of the paint film surface.
overview photoinitiator (Photoinitiator, abbreviated PI) is a key component of photocurable materials, which plays a decisive role in the photocuring speed of photocurable materials. Photoinitiator is a kind of material that can absorb radiation energy, undergo photochemical changes after excitation, and produce active intermediates (free radicals or cations) with the ability to initiate polymerization. Photoinitiators can be divided into ultraviolet initiators (ultraviolet light absorption region 250 ~ 420nm) and visible light initiators (visible light absorption region 400 ~ 700nm) due to different radiation energy. Photoinitiators can be divided into free radical photoinitiators and cationic photoinitiators due to the different active intermediates produced. Free radical photoinitiators can be divided into two types: cracking photoinitiators and hydrogen-dehydrating photoinitiators due to the different mechanisms of producing free radicals. At present, the light curing technology is mainly ultraviolet curing, and the photoinitiator used is ultraviolet light initiator.
use UV curable varnish and paint systems, such as wood, paper, metal, plastic, optical fiber and printing ink and prepreg systems
Last Update:2024-04-10 22:29:15
Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)-
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Phosphine oxide, phenyl bis (2,4,6-trimethylbenzoy)-
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