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TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE

tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane

CAS: 76782-82-6

Molecular Formula: C9H18OSi

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TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE - Names and Identifiers

Name tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane
Synonyms t-ButylDimethylPropargyloxysilane
3-(tert-Butyldimethylsilyloxy)propyne
tert-Butyldimethylsilyl propargyl ethe
Tert-butyl-dimethyl-prop-2-ynoxysilane
TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE
TERT-BUTYLDIMETHYL(PROP-2-YNYLOXY)SILANE
tert-Butyldimethyl(2-propyn-1-yloxy)silane
tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane
tert-Butyl(dimethyl)(prop-2-yn-1-yloxy)silane
Propargyl alcohol tert-butyldimethylsilyl ether
silane, (1,1-dimethylethyl)dimethyl(2-propyn-1-yloxy)-
CAS 76782-82-6
InChI InChI=1/C9H18OSi/c1-7-8-10-11(5,6)9(2,3)4/h1H,8H2,2-6H3
InChIKey ZYDKYFIXEYSNPO-UHFFFAOYSA-N

TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE - Physico-chemical Properties

Molecular FormulaC9H18OSi
Molar Mass170.32
Density0.84 g/mL at 25 °C (lit.)
Boling Point40 °C/8 mmHg (lit.)
Flash Point108°F
Solubility Diethyl Ether, Ethyl Acetate, Hexane
Vapor Presure3.51mmHg at 25°C
AppearanceOil
Specific Gravity0.84
ColorColorless
Sensitive7: reacts slowly with moisture/water
Refractive Indexn20/D 1.429(lit.)

TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE - Risk and Safety

Risk Codes10 - Flammable
Safety Description16 - Keep away from sources of ignition.
UN IDsUN 1993 3/PG 3
WGK Germany3

TERT-BUTYLDIMETHYL(2-PROPYNYLOXY)SILANE - Introduction

tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane is an organosilicon compound with the chemical formula C9H18OSi, which contains one propargyloxy group and one tert-butyl group in the molecule. The following is a description of the properties, uses, preparation and safety information of the compound:

1. nature:
-Appearance: colorless transparent liquid
-Molecular weight: 170.32g/mol
-Boiling Point: 85-87°C
-Density: 0.80 g/mL
-Solubility: Soluble in non-polar solvents such as benzene and ether

2. use:
-As an organic silicon compound, it is often used to synthesize functional materials;
-can be used as a reagent in organic synthesis, such as a reagent for oxidation, reduction and substitution reactions;
-In chemical research, it can be used as an intermediate in organic synthesis reactions.

3. preparation method:
- tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane can be prepared by chemical synthesis, the specific steps are as follows:
-Step 1: Use the malodorous gas as the solvent, and introduce the gas into the reactor through the pipeline;
-Step 2: A Zhan-blown acid treatment agent generates silver ions from silver compounds, and in the presence of silver ions, an acid-catalyzed acetylenic silver addition reaction occurs with acetylenic alcohols to generate acetylenic hydrocarbons;
-step 3: catalytically adding the alkyne obtained in step 2 to tert-butanol to generate propargyl alcohol;
-Step 4: Use aluminum-lithium alloy to reduce propargyl alcohol to propargyl hydrocarbon;
-Step 5: React propargyl with dimethylchlorosilane through silicon chemical reaction to obtain the final product tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane.

4. Safety Information:
- tert-butyl(dimethyl)(prop-2-yn-1-yloxy)silane is relatively stable and is not prone to fire or explosion under normal use conditions.
-but it may be irritating and corrosive to the eyes and skin, use should wear personal protective equipment, such as glasses and gloves.
-Avoid inhaling its vapors or contacting its liquids to avoid discomfort or damage to health.
-In use or storage, should comply with the relevant safety guidelines and regulations.

Please note that the above information is for reference only. Please follow safe operations when using the compound and refer to the exact chemical substance safety data sheet (MSDS).
Last Update:2024-04-10 22:29:15
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View History
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