Tetrapropylammonium perruthenate

Tetrapropylammonium perruthenate - Names and Identifiers

Name	Tetra-n-propylammonium perruthenate(VII)
Synonyms	TPAP tetrapropylammonium oxido-trioxo-ruthenium TerapropylaMMoniuMperruthenate Tetrapropylammonium perruthenate TETRAPROPYLAMMONIUM PERRUTHENATE TETRA-N-PROPYLAMMONIUM PERRUTHENATE Tetrapropylammonium tetraoxoruthenate Tetra-n-propylammonium perruthenate(VII) TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII) 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru
CAS	114615-82-6
EINECS	628-415-8
InChI	InChI=1/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
InChIKey	NQSIKKSFBQCBSI-UHFFFAOYSA-N

Tetrapropylammonium perruthenate - Physico-chemical Properties

Molecular Formula	C12H28NO4Ru
Molar Mass	351.43
Melting Point	~160 °C (dec.) (lit.)
Water Solubility	Insoluble in water.
Solubility	Methanol (Slightly)
Appearance	crystal
Color	green
Storage Condition	Inert atmosphere,2-8°C
Stability	store cold
Sensitive	Hygroscopic
MDL	MFCD00074914
Use	Soluble, non-volatile, air-stable, mild catalysts that can be used with appropriate co-oxidants in stoichiometric terms or as catalytic applications. An oxidant used to convert N,N′-dihydroxyimidazoline into nitroxide radicals. Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborate to aldehydes and ketones without? concomitant cleavage of the carbon-boron bond.

Tetrapropylammonium perruthenate - Risk and Safety

Risk Codes	R5 - Heating may cause an explosion R8 - Contact with combustible material may cause fire R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing.
UN IDs	UN 1479 5.1/PG 2
WGK Germany	3
FLUKA BRAND F CODES	3-10
HS Code	28439000
Hazard Class	5.1
Packing Group	III

Tetrapropylammonium perruthenate - Reference Information

use

soluble, non-volatile, air-stable mild catalyst, can be used with appropriate co-oxidizer according to stoichiometry or as catalytic use. An oxidant used to convert N,N′-dihydroxyimidazoline into nitroxide radicals. Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborate to aldehydes and ketones without? concomitant cleavage of the carbon-boron bond.

Last Update：2024-04-10 22:29:15