Thiocyclam Hydrogen Oxalate

Name	Thiocyclam hydrogen oxalate
Synonyms	Evisect Sulfoxane Thiocyclam hydrogen oxalate ThiocyclaM-hydrogen oxalate solution THIOCYCLAM HYDROGEN OXALATE STANDARD N,N-Dimetnyl-1,2,3-trithian-5-ylamine Bis(1,2,3-trithiacyclohexyldimethylammon N,N-dimethyl-1,2,3-trithiaxan-5-ylamine oxalate bis(1,2,3-trithiacyclohexyldimethylammonium) oxalate thiocyclam-oxalate
CAS	31895-22-4
EINECS	250-859-2

Molecular Formula	C5H11NS3.C2H2O4
Molar Mass	271.38
Flash Point	130°C
Water Solubility	16.3 g l-1(20 °C, pH 6.8)
Vapor Presure	5.45 x 10-4 Pa (20 °C)
Appearance	neat
BRN	4771240
pKa	3.95 (acid), 7.0 (base)
Storage Condition	0-6°C
Physical and Chemical Properties	Colorless and odorless crystals. The melting point is 125-128 ℃ (decomposition), and the vapor pressure at 20 ℃ is 5.3 × 10-2Pa. The solubility in water at 23 ℃ is 84g/L, acetone 500mg/L, ethanol 1.9g/L, methanol 17g/L, xylene <10g/L, insoluble in kerosene. Time to decompose 50%(40ml/L) in buffer solution at 22-24 ℃: 42d at pH = 5 and 11d at pH = 7-9. It will not degrade after being placed at 50 ℃ in the dark for four weeks.

Risk Codes	R21/22 - Harmful in contact with skin and if swallowed. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description	S36/37 - Wear suitable protective clothing and gloves. S46 - If swallowed, seek medical advice immediately and show this container or label. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
UN IDs	2588
WGK Germany	3
RTECS	YL8300000
Hazard Class	6.1(b)
Packing Group	III

EPA chemical substance information	information provided by: ofmpeb.epa.gov (external link)
Use	selective insecticide. It has the effects of stomach poison, contact killing and internal absorption. Control Scale order and coleopteran pest lasting for 7-14 days, but also control parasitic nematodes, such as rice White nematode, some crops of rust and white ear disease also have a certain control effect.
production method	3-N, n-dimethylamino-1 is prepared from allyl chloride as starting material by amination and chlorination, 2-N, n-dimethylamino-1-thiosulfate sodium-3-thiosulfate propane (referred to as monosodium salt) was obtained by reaction of 2-N, n-dimethylamino-1-thiosulfate hydrochloride and sodium thiosulfate, the salt is obtained.
category	pesticide
toxicity grade	high toxicity
Acute toxicity	oral-rat LD50: 195 mg/kg; Oral-mouse LD50: 156 mg/kg
flammability hazard characteristics	toxic nitrogen oxide and sulfur oxide gases from combustion
storage and transportation characteristics	The warehouse is ventilated and dried at low temperature; It is stored and transported separately from food raw materials
extinguishing agent	dry powder, foam, sand

Last Update：2024-04-09 18:58:34

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