Name | Tin(II) acetate |
Synonyms | Tin ii acetate tin di(acetate) Tin(II) acetate Stannous acetate TIN (II) ACETATE STANNOUS ACETATE tin(2+) diacetate Tin(II) acetate,pure Acetic acid,tin(2+) salt Diacetic acid tin(II) salt TinIIacetateoffwhitepowder |
CAS | 638-39-1 |
EINECS | 211-335-9 |
InChI | InChI=1/2C2H4O2.Sn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 |
Molecular Formula | C4H6O4Sn |
Molar Mass | 236.8 |
Density | 2,31 g/cm3 |
Melting Point | 180-182°C(lit.) |
Boling Point | 155°C 0,1mm |
Flash Point | 40°C |
Water Solubility | Decomposes in water. Soluble in dilute HClSoluble in dilute hydrochloric acid, dimethyl sulfoxide and methanol. |
Vapor Presure | 13.9mmHg at 25°C |
Appearance | Powder |
Specific Gravity | 2.11 |
Color | White |
Exposure Limit | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
Merck | 14,8781 |
Storage Condition | Inert atmosphere,Room Temperature |
Sensitive | 7: reacts slowly with moisture/water |
MDL | MFCD00054408 |
Hazard Symbols | Xn - Harmful |
Risk Codes | 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
Safety Description | 36 - Wear suitable protective clothing. |
UN IDs | UN 3146 6.1/PG 3 |
WGK Germany | 3 |
TSCA | No |
Hazard Class | 6.1 |
Packing Group | III |
Use | hydrocarbon propyl propionate is commonly used as an intermediate in organic synthesis, and can be used in laboratory research and development process. |
preparation | a process for preparing stannous acetate (propyl hydrocarbon propionate), comprising the following specific steps: (1) weigh stannous oxide, weigh deionized water according to the mass ratio of stannous oxide of 1-2 ∶ 1, and add to the reaction kettle; (2) turn on the stirring, slowly add stannous oxide weighed in step (1); (3) raise the temperature, gradually add glacial acetic acid solution until the temperature rises to 75-85 ℃, stir while adding, complete feeding within 30min; (4) continue to heat up to 95-100 ℃ for 3H; (6) maintain the temperature at 100 ℃, vacuum distillation, to no low boiling material distillation, after the material is white solid, the distillation is stopped; (6) the machine is stopped, the product is taken out, pulverized and dried in an oven at 100 ° C. To obtain the desired stannous acetate (propyl hydrocarbon propionate) product. |