delta-Vitamin E
[2R[2R*(4R*,8R*)]]-3,4-dihydro-2,8-dimethyl-2-(4,8,12-trimethyltridecyl)-2H-benzopyran-6-ol
CAS: 119-13-1
Molecular Formula: C27H46O2
delta-Vitamin E - Names and Identifiers
| Name | [2R[2R*(4R*,8R*)]]-3,4-dihydro-2,8-dimethyl-2-(4,8,12-trimethyltridecyl)-2H-benzopyran-6-ol |
| Synonyms | E 309 delta-Vitamin E D-Delta-Tocopherol delta-D-Tocopherol [2R[2R*(4R*,8R*)]]-3,4-dihydro-2,8-dimethyl-2-(4,8,12-trimethyltridecyl)-2H-benzopyran-6-ol 3,4-dihydro-2,8-dimethyl-2-(4,8,12-trimethyltridecyl)-,[2R-[2R*(4R*,8R*)]]-2H-1-Benzopyran-6-ol |
| CAS | 119-13-1 |
| EINECS | 204-299-0 |
| InChI | InChI=1/C27H46O2/c1-20(2)10-7-11-21(3)12-8-13-22(4)14-9-16-27(6)17-15-24-19-25(28)18-23(5)26(24)29-27/h18-22,28H,7-17H2,1-6H3 |
| InChIKey | GZIFEOYASATJEH-VHFRWLAGSA-N |
delta-Vitamin E - Physico-chemical Properties
| Molecular Formula | C27H46O2 |
| Molar Mass | 402.65 |
| Density | 0.935g/cm3 |
| Melting Point | <25℃ |
| Boling Point | 504.3°C at 760 mmHg |
| Specific Rotation(α) | 25546 +3.4° (c = 15.5 in alc); 25546 +1.1° (c = 10.9 in benzene) |
| Flash Point | 200.1°C |
| Solubility | Insoluble in water, easily soluble in acetone and ethanol |
| Vapor Presure | 8.54E-11mmHg at 25°C |
| Appearance | Morphological Viscous Liquid |
| Color | 颜色 Clear yellow to brownish |
| pKa | 10.70±0.40(Predicted) |
| Storage Condition | -20°C |
| Sensitive | Sensitive to air |
| Refractive Index | 1.494 |
| MDL | MFCD00067686 |
| Physical and Chemical Properties | Bioactivity ()-Delta-Tocopherol (8-Methyltocol) is a delta configuration of fat-soluble vitamin E with oral bioavailability. It is mostly found in soybean and corn oil and has potential antioxidant activity. |
| Use | Uses ()-δ-tocopherol can be used as an antioxidant. Vitamin E helps prevent polyunsaturated fatty acids and phospholipids from being oxidized, so it can maintain the integrity of the cell membrane. It can protect vitamin A from oxidative damage and strengthen its effect, vitamin E and iodine compounds. It has been proven to prevent symptoms related to vitamin E deficiency. Some research reports show that it is related to cancer prevention and anti-aging, but it has not been widely confirmed. The effect of preventing excessive aggregation of platelets improves the stability of the red blood cell membrane and the synthesis of red blood cells. |
delta-Vitamin E - Risk and Safety
| Safety Description | 24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| HS Code | 29329990 |
delta-Vitamin E - Upstream Downstream Industry
| Downstream Products | 3,4-dihydro-2,7,8-trimethyl-2-(4,8,12-trimethyltridecyl)-2H-benzopyran-6-ol |
delta-Vitamin E - Nature
| specific rotation | 25546 3.4° (c = 15.5 in alc); 25546 1.1° (c = 10.9 in benzene) |
| Solubility | Chloroform (Sparingly), Ethanol (Slightly, Sonicated), Ethyl Acetate (Slightly), |
Last Update：2024-04-09 01:59:50
delta-Vitamin E - Uses and synthesis methods
natural vitamin e
Natural vitamin E is a mixture, mainly composed of four tocopherol homologs derived from maternal phenols, including d-α-tocopherol, d-β-tocopherol, d-& gamma;-Tocopherol and d-& delta;-Tocopherol, they all have saturated C16 side chains, only the number and position of methyl groups on the benzene ring are different. Although their structures are very similar, their biological activities are different, which are d-α-tocopherol> d-β-tocopherol> d-& gamma;-tocopherol> d-& delta;-tocopherol, while the antioxidant activity is d-& delta;-tocopherol is the highest.
Preparation
100g of mixed tocopherol concentrated solution containing 40.5% is added into 500ml of 95% ethanol, and after cold analysis and filtration, a resin adsorption column (& phi) is installed at normal temperature. 50mm * 600mm), filled with strong alkaline ionic resin, model PA306S, particle size 60-100 mesh, resin after transformation treatment, resin layer height 300mm, resin column volume (BV) of about 0.6L. After the sample is adsorbed, 1.5L(2.5BV) of 95% ethanol is used to rinse the impurity not adsorbed by the resin, then 2.4L0.01-0.05mol/L of carbon dioxide ethanol solution is used to desorb, the first effluent is collected, the solvent is recovered and distilled to obtain 34.5g of mixed tocopherol, of which the total tocopherol content is 93.5%,d-& delta;-The relative content of tocopherol monomer is 28.3%. Then desorb with 1.2L0.15-0.2mol/L carbon dioxide ethanol solution, collect the second effluent, and recover the solvent to obtain 6.4gd-& delta;-tocopherol monomer, in which the total tocopherol content is 91.3%,d-& delta;-The relative content of tocopherol monomer is 89.6%, and the yield of total tocopherol is 94.1%.
Target
Human Endogenous Metabolite
Last Update：2024-04-09 20:52:54
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Product Name: [2R[2R*(4R*,8R*)]]-3,4-dihydro-2,8-dimethyl-2-(4,8,12-trimethyltridecyl)-2H-benzopyran-6-ol Request for quotation
CAS: 119-13-1
Tel: 0086-551-65418684
Email: sales@tnjchem.com
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Mobile: 0086 189 4982 3763
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CAS: 119-13-1
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
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Product Name: (+)-δ-Tocopherol Visit Supplier Webpage Request for quotationCAS: 119-13-1
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