Use | Uses for polymer catalysts |
synthesis of polymer 1: under the protection of room temperature and nitrogen, 0.048ml (1S, 2S)-( )-cyclohexanediamine and 84.8g Na2CO3 are suspended in 5ml benzene, under stirring, 4ml benzene solution of 100mg ferrocene diformyl chloride is added, yellow precipitate is generated in about 3min, stirred for 1h, filtered precipitate is washed with benzene, and vacuum drying.
Synthesis of polymer 2: under the protection of room temperature and nitrogen, 60mg (R)-( )-1, 1-2-naphthylamine is added into 6ml of distilled water, then 30mg NaOH is added, and then 66mg of benzene solution of ferrocenyl chloride is added dropwise 3ml. After about 1 hour, yellow solution is generated from red solution to precipitate, stirred for 2 hours, filtered, precipitated.