Molecular Formula | C9H8Cl2O3 |
Molar Mass | 235.06 |
Density | 1.421±0.06 g/cm3(Predicted) |
Melting Point | 124° |
Boling Point | 348.3±27.0 °C(Predicted) |
Specific Rotation(α) | 21D +26.6° (c = 1.23 in ethanol) |
Flash Point | 2°C |
Appearance | neat |
Merck | 13,3104 |
BRN | 5265110 |
pKa | 3.03±0.10(Predicted) |
Storage Condition | Sealed in dry,Room Temperature |
Physical and Chemical Properties | The pure product is a crystalline solid. M. p.122 ℃, vapor pressure 6.2 × 105Pa (20 ℃), [α]21D 26.6 o. Solubility at 20 ℃: acetone> 1000 g/kg, ethyl acetate 560 g/kg, ethanol> 1000 g/kg, toluene 46 g/kg, water 0.59g/L (pH = 7). Partition coefficient 89 (pH = 4.6),pKa3.0. Stable to light, stable at pH 3~9. |
Risk Codes | R22 - Harmful if swallowed R38 - Irritating to the skin R41 - Risk of serious damage to eyes R43 - May cause sensitization by skin contact R36 - Irritating to the eyes R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R11 - Highly Flammable |
Safety Description | S24 - Avoid contact with skin. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection S36 - Wear suitable protective clothing. S16 - Keep away from sources of ignition. S36/37 - Wear suitable protective clothing and gloves. |
UN IDs | UN1648 3/PG 2 |
WGK Germany | 1 |
RTECS | UA2458860 |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
toxicity | Acute oral LD50>825~1470mg/kg in rats, acute percutaneous LD50>4000mg/kg in rats, rats with acute inhalation of LC50>7.4mg/L (4H). Rats fed 2 years test dose of 3.6mg/kg per day. Trout LC50100 ~ 220mg/L (96H). The oral LD50 of quails was 250 ~ 500mg/kg. Safe for bees. |
Use | phenoxypropionic acid herbicide, which belongs to hormone-type systemic herbicide. It has special effects on Polygonum palmatum and Polygonum Chunyu, and it is effective for the pig, and it is not effective for the pig. The recommended dosage for cereal crops is 1.2~1.5kg/hm2. Jing 2,4-drop propionic acid is an aryloxyalkyl acid herbicide, which is a hormone-type inhalation herbicide and is particularly effective for the spring and the horse. It can also be used to prevent the pig from suffering and breeding, but it has a certain effect on the flat storage. In cereal crops alone, the dosage of 1.2~1.5 (a. I.)/ha, or in combination with other herbicides. Can also be used at lower doses to prevent Apple fruit loss. |
production method | methyl L-2-chloropropanoate ([α]20D-25.2 o) and methanol, 33% aqueous sodium hydroxide solution is mixed below 40 ℃, added to the mixture of 2, 4-dichlorophenol, sodium hydroxide and water at 90 ℃, heated at 90 ℃ for 1H, 4-drop propionate sodium salt. D-isomer> 87%. High 2,4-drop propionic acid can produce various esters. dichlorprop-p-isobutyl the molecular formula is C13H16Cl2O3;dichlorprop-p-dimethylammonium the molecular formula is c11h15cshi NO3,C.A.NO. [104786-87-0]. |