ferroceneboronic acid

ferroceneboronic acid - Names and Identifiers

Name	ferroceneboronic acid
Synonyms	NSC 119337 FERROCENEBORONIC ACID ferroceneboronic acid Ferrocenylboronic acid ferrocenemetaboric acid (Boronocyclopentadienyl)cyclopentadienyl iron Ferroceneboronic acid (contains varying amounts of anhydride) N,N-dimethyl-3-(6,7,8,9-tetrahydropyrido[4,3-b]indol-5-yl)-1-propanamine dihydrochloride
CAS	12152-94-2
EINECS	235-272-1
InChI	InChI=1/C5H6BO2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4,7-8H;1-5H;/q2*-1;+2

ferroceneboronic acid - Physico-chemical Properties

Molecular Formula	C10H11BFeO210*
Molar Mass	229.85
Melting Point	145-150 °C (dec.) (lit.)
Boling Point	267.1°C at 760 mmHg
Flash Point	115.3°C
Solubility	slightly sol. in Ether
Vapor Presure	0.00113mmHg at 25°C
Appearance	powder to crystal
Color	White to Yellow to Orange
Storage Condition	2-8℃
MDL	MFCD00059074

ferroceneboronic acid - Risk and Safety

Hazard Symbols	Xi - Irritant
Risk Codes	36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves.
WGK Germany	3
HS Code	29319090

ferroceneboronic acid - Reference Information

Use

Ferrocene boric acid, as a commercial reagent, can be used not only for the construction of carbon-carbon bonds, but also for boron-silicon bonds, Carbon-sulfur bonds and other chemical bonds containing heteroatoms. At the same time, compared with other ferrocene reagents, ferrocene boric acid has obvious advantages in reaction steps and atomic economy in transition metal-catalyzed coupling reactions. Therefore, ferrocene boric acid is widely used in the synthesis of ferrocene derivatives.

overview

the disclosure of ferrocene structure is an important breakthrough in the field of chemistry, which promoted the birth and development of modern metal organic chemistry. Ferrocene quickly attracted scientists to think about its fascinating chemical properties. Researchers began to develop synthetic methods using ferrocene derivatives and discovered their wide range of uses in the scientific field. In fact, more than 60 years after the discovery of ferrocene, ferrocene chemistry is still a very active research field. There are many reasons for this long-term sustained concern about ferrocene. First of all, ferrocene has a perfect sandwich structure, which breaks the traditional understanding of the nature of metal-carbon bonds. On the other hand, ferrocene and its derivatives show unusual stability to moisture, oxygen and many chemicals, as well as other unique electrochemical properties. At present, the commonly used reagents for introducing ferrocene groups into molecules include ferrocene, ferrocene formaldehyde, etc. The above reagents are mostly used for the formation of carbon-carbon bonds.

Last Update：2024-04-10 22:29:15