propylboronic acid
n-Propylboronic acid
CAS: 17745-45-8
Molecular Formula: C3H9BO2
propylboronic acid - Names and Identifiers
| Name | n-Propylboronic acid |
| Synonyms | Propylboronic PROPYLBORONIC ACID propylboronic acid Propaneboronic acid RARECHEM AH PB 0255 N-PROPYLBORONIC ACID n-Propylboronic acid Propylboronic Acid (contains varying aMounts of Anhydride) |
| CAS | 17745-45-8 |
| EINECS | 681-581-3 |
| InChI | InChI=1/C3H9BO2/c1-2-3-4(5)6/h5-6H,2-3H2,1H3 |
propylboronic acid - Physico-chemical Properties
| Molecular Formula | C3H9BO2 |
| Molar Mass | 87.91 |
| Density | 0.925±0.06 g/cm3(Predicted) |
| Melting Point | 105-108°C |
| Boling Point | 170.8±23.0 °C(Predicted) |
| Flash Point | 57.1°C |
| Solubility | DMSO (Slightly), Methanol (Slightly) |
| Vapor Presure | 0.461mmHg at 25°C |
| Appearance | White to light yellow crystal powder |
| Color | White to off-white |
| BRN | 1731884 |
| pKa | 10.31±0.43(Predicted) |
| Storage Condition | Inert atmosphere,Store in freezer, under -20°C |
| Sensitive | Air Sensitive |
| Refractive Index | 1.388 |
| MDL | MFCD01074564 |
propylboronic acid - Risk and Safety
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R22 - Harmful if swallowed |
| Safety Description | S37/39 - Wear suitable gloves and eye/face protection S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | No |
| HS Code | 29319090 |
| Hazard Class | IRRITANT |
propylboronic acid - Introduction
n-Propylboronic acid, also known as propyl boronic acid or benzyl boronic acid, has the following properties:
1. Physical properties: n-Propylboronic acid is a colorless liquid with a special aroma. It is soluble in water and many organic solvents, such as alcohols, ethers, etc.
2. Chemical properties: n-Propylboronic acid is a boron-containing organic compound. It acts as an acid and can react with a base to form the corresponding salt. It can also perform nucleophilic substitution reactions and participate in some organic synthesis reactions.
3. Application: n-Propylboronic acid is commonly used as catalyst and ligand in organic synthesis. It can catalyze many organic reactions, such as hydrogenation, oligomerization, isomerization and so on. In addition, it is used to prepare other organoboron compounds, such as boronates and borates.
4. Preparation method: n-Propylboronic acid can be obtained by the reaction of propyl magnesium bromide with boron trichloride. After the reaction, n-Propylboronic acid is obtained by hydrolysis.
5. Safety Information: n-Propylboronic acid under normal conditions of use, with low toxicity and corrosion. However, it is still necessary to follow the safety procedures and avoid contact with skin and eyes. Wear appropriate protective gloves, glasses and laboratory clothing during use. At the same time, it should be stored in a sealed container, avoiding contact with air and humidity. If accidentally touched or accidentally eaten, seek medical attention immediately.
1. Physical properties: n-Propylboronic acid is a colorless liquid with a special aroma. It is soluble in water and many organic solvents, such as alcohols, ethers, etc.
2. Chemical properties: n-Propylboronic acid is a boron-containing organic compound. It acts as an acid and can react with a base to form the corresponding salt. It can also perform nucleophilic substitution reactions and participate in some organic synthesis reactions.
3. Application: n-Propylboronic acid is commonly used as catalyst and ligand in organic synthesis. It can catalyze many organic reactions, such as hydrogenation, oligomerization, isomerization and so on. In addition, it is used to prepare other organoboron compounds, such as boronates and borates.
4. Preparation method: n-Propylboronic acid can be obtained by the reaction of propyl magnesium bromide with boron trichloride. After the reaction, n-Propylboronic acid is obtained by hydrolysis.
5. Safety Information: n-Propylboronic acid under normal conditions of use, with low toxicity and corrosion. However, it is still necessary to follow the safety procedures and avoid contact with skin and eyes. Wear appropriate protective gloves, glasses and laboratory clothing during use. At the same time, it should be stored in a sealed container, avoiding contact with air and humidity. If accidentally touched or accidentally eaten, seek medical attention immediately.
Last Update：2024-04-09 21:11:58
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