Name | Strontium titanate |
Synonyms | Strontium titanate STRONTIUM TITANATE titanate, strontium Strontium Titanate I STRONTIUM (II) TITANATE STRONTIUM TITANIUM OXIDE strontium titanium trioxide distrontium tetraoxidotitanium strontium dioxido(oxo)titanium STRONTIUM TITANIUM OXIDE SUBSTRATE Strontiumtitanatewhitetooffwhitepowder |
CAS | 12060-59-2 |
EINECS | 235-044-1 |
InChI | InChI=1/4O.2Sr.Ti/q4*-1;2*+2;/rO4Ti.2Sr/c1-5(2,3)4;;/q-4;2*+2 |
InChIKey | VEALVRVVWBQVSL-UHFFFAOYSA-N |
Molecular Formula | O3SrTi |
Molar Mass | 183.49 |
Density | 4.81g/mLat 25°C(lit.) |
Melting Point | 2060°C(lit.) |
Water Solubility | It is insoluble in water and most solvents. |
Solubility | H2O: insoluble |
Vapor Presure | 0Pa at 25℃ |
Appearance | White-like to light brown crystals or powders |
Specific Gravity | 4.81 |
Color | White to off-white |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Refractive Index | nD 2.409 |
MDL | MFCD00049554 |
Physical and Chemical Properties | White cubic crystals. The relative density was 5.13. Melting point 2080 °c. With high refractive index and high dielectric constant. Toxic! |
Use | In 1955, the National Reed Company of the United States used the flame melting method to make an artificial gem without a natural counterpart. Its chemical composition is srtio3. equiaxed crystal system. Colorless. Refractive index n = 2.409. Dispersion 0.190. Relative density 5.13. Hardness 5~6. No cleaway, the fracture shell-like. No fluorescence under ultraviolet light. This artificial gem is often cut and ground into emerald type, which is a very good diamond substitute. Strontium titanate (Sr Ti O3) has a typical perovskite structure and is a widely used electronic functional ceramic material. It has the advantages of high dielectric constant, low dielectric loss and good thermal stability, and is widely used in electronic, mechanical and ceramic industries. At the same time, as a functional material, strontium titanate has a forbidden band width |
WGK Germany | 3 |
TSCA | Yes |
strontium titanate is a colorless and transparent cubic crystalline powder. Relative density 5.1; Melting point 2080 ℃; Specific heat capacity 0. 62J/(g.K), microhardness 595kg/mm2. Soluble in concentrated hydrochloric acid, nitric acid and hydrofluoric acid, insoluble in water and alkali solution.
with strontium carbonate and titanium dioxide as raw materials. Strontium carbonate, titanium dioxide and other additives in an amount of the same substance are mixed and ground, extruded, put into an electric furnace, and calcined at 1100 to 1200 ° C. For 2.5 to 3 hours. The calcined material was pulverized, then ground, pickled, filtered, washed, and dried to obtain strontium titanate. Or strontium chloride, titanium tetrachloride, oxalic acid as raw materials, the reaction to obtain a white precipitate, filtered, washed with deionized water to no chloride ion, then anhydrous ethanol washing dispersion, dehydration, drying at 700 deg C, it can be calcined at 800 °c.
for the production of medium and high voltage ceramic capacitors, grain boundary capacitors, PTC thermistors and multi-function sensing and other electronic components. It is also used to automatically adjust the heating element and make the degaussing element, which can reduce the Curie temperature of the element. It can also be used in the manufacture of optical materials and artificial precious stones.
lined with polyethylene plastic bag, external plywood drum or woven bag packaging. Each barrel (bag) net weight 25kg, 50kg. Should be stored in a cool, ventilated, dry, clean warehouse. Sealed storage, moisture-proof. During transportation, it should be protected from rain and sunlight. When loading and unloading should be light to prevent packaging damage. In case of fire, it can be suppressed by water, sand and all kinds of fire extinguishing. See barium titanate for toxicity and protection.
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
toxicity | see barium titanate. |
use | is an important raw material for the electronics industry to automatically adjust heating elements and manufacture components with degaussing effect. In the ceramic field, it is used to manufacture ceramic capacitors, piezoelectric ceramic materials, ceramic sensitive components, and microwave ceramic components. It can also be used as pigment, enamel, heat-resistant material and insulating material. Strontium titanate single crystal can be used as optical materials and artificial gemstones. In 1955, the National Reed Company of the United States used the flame melting method to make an artificial gem without a natural counterpart. Its chemical composition is srtio3. equiaxed crystal system. Colorless. Refractive index n = 2.409. Dispersion 0.190. Relative density 5.13. Hardness 5~6. No cleavage, shell-like fracture. No fluorescence under ultraviolet light. This artificial gem is often cut and ground into emerald type, which is a very good diamond substitute. Strontium titanate (Sr Ti O3) has a typical perovskite structure and is a widely used electronic functional ceramic material. It has the advantages of high dielectric constant, low dielectric loss and good thermal stability, and is widely used in electronic, mechanical and ceramic industries. At the same time, as a functional material, strontium titanate has a high forbidden band width |
production method | oxalic acid precipitation method compiles high purity titanium tetrachloride, strontium chloride and high purity oxalic acid into a solution with a certain concentration, then strontium chloride and titanium tetrachloride are prepared into a strontium-titanium mixed solution according to a certain ratio, slowly added into the oxalic acid solution at 60~70 ℃, and reacted for about 1 hour to obtain strontium titanium oxalate [SrTiO(C2O4)?4H2O] precipitation, after washing, drying, calcination, the preparation of strontium titanate powder. Its SrC12 TiCl4 2H2C2O4 5H2O → SrTiO(C2O4)2?4H2O ↓ 6HClSrTiO(C2O4)2?4H2O → SrTiO3 4H2O 2CO2 ↑ 2CO |