1,1-bis(diphenyphosphino)ferrocene
1,1-bis(diphenyphosphino)ferrocene
CAS: 12150-46-8
Molecular Formula: C34H28FeP2
1,1-bis(diphenyphosphino)ferrocene - Names and Identifiers
| Name | 1,1-bis(diphenyphosphino)ferrocene |
| Synonyms | DPPF iron 1,1-bis(diphenyphosphino)ferrocene 1,1-Ferrocenebis(diphenylphosphine) 1,1-Bis(diphenylphosphino)ferrocene 1,1-Ferrocenediyl-bis(diphenylphosphine) 1-cyclopenta-2,4-dienyl-diphenyl-phosphane bis(2-diphenylphosphanylcyclopenta-2,4-dien-1-yl)iron |
| CAS | 12150-46-8 |
| EINECS | 430-420-3 |
| InChI | InChI=1/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/rC34H28FeP2/c1-5-15-27(16-6-1)36(28-17-7-2-8-18-28)33-25-13-23-31(33)35-32-24-14-26-34(32)37(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,31-32H |
1,1-bis(diphenyphosphino)ferrocene - Physico-chemical Properties
| Molecular Formula | C34H28FeP2 |
| Molar Mass | 554.379 |
| Melting Point | 181-183℃ |
| Water Solubility | Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water. 7: reacts slowly with moisture/water |
| Appearance | yellow to orange crystal |
| Storage Condition | 2-8°C |
| Stability | Stable. Incompatible with strong oxidizing agents. Air Sensitive |
| Physical and Chemical Properties | Melting point 181-183°C. |
| Use | A ligand for the synthesis of oxazepine ring system in a palladium-catalyzed coupling reaction; Preparation of novel functionalized furan derivatives by continuous C- C and C- O bonding reactions of palladium phosphonates; Transition metal complexes, an effective catalyst for cross-coupling reactions of Grignard reagents with organic halides and related compounds; A diphosphine ligand, complexes with transition metals can be used as C- C/C-N/C-O coupling reactions and other organic synthesis catalysts |
1,1-bis(diphenyphosphino)ferrocene - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | R25 - Toxic if swallowed |
| Safety Description | S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | 3467 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10-23 |
| TSCA | No |
| HS Code | 29319090 |
| Hazard Class | IRRITANT |
1,1-bis(diphenyphosphino)ferrocene - Upstream Downstream Industry
1,1-bis(diphenyphosphino)ferrocene - Introduction
Melting point 181-182°C (dec.)(lit.)
Storage conditions 2-8°C
morphological crystal
color yellow to orange
water solubility Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
hydrolysis sensitivity 7: reacts slowly with moisture/water
Sensitivity Air Sensitive
stability stable. Incompatible with strong oxidizing agents.
application
1,1 '-bis (diphenylphosphine) ferrocene is used to synthesize ligands of oxazepine ring system in palladium-catalyzed coupling reaction; novel functionalized furan derivatives are prepared by continuous C- C of palladium phosphinate and C- O bonding reaction; transition metal complex, an effective catalyst for cross-coupling reaction between Gliya reagent (Grignardreagents) and organic halides and related compounds.
Uses Used for the synthesis of ligands of oxazepine ring systems in palladium-catalyzed coupling reactions; preparation of novel functionalized furan derivatives through continuous C- C of palladium phosphinates and C- O bonding reactions; transition metal complexes, Used as an effective catalyst for the cross-coupling reaction of Gliya reagents (Grignard reagents) with organic halides and related compounds; a diphosphine ligand, complexes with transition metals can be used as organic synthesis catalysts such as C- C/C-N/C-O coupling reactions
Use organometallic catalyst (ligand). New functionalized furan derivatives were prepared by palladium-phosphine catalyzed C- C and C- O bond sequential bonding reaction.
safety information
dangerous goods mark T,Xi,Xn
Hazard category code 25-36/37/38-20/21/22
Safety instructions 22-24/25-45-28A-36-26-36/37/39
Dangerous Goods Transport No. 3467
WGK Germany 3
F 10-23
TSCA No
HazardClass IRRITANT
customs code 29319090
Last Update：2024-04-10 22:29:15
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View History
1,1-bis(diphenyphosphino)ferrocene
1-(2,6-Dichloro-3-fluorophenyl)ethanol
季戊四醇四(2-氰基-3,3-二苯丙烯酸酯)
5-Decen-1-ol, (5Z)-
1-(2,6-Dichloro-3-fluorophenyl)ethanol
季戊四醇四(2-氰基-3,3-二苯丙烯酸酯)
5-Decen-1-ol, (5Z)-
Raw Materials for 1,1-bis(diphenyphosphino)ferrocene
Sodium hydroxide
Ethyl acetate
n-Butyllithium
N,N,N',N'-Tetramethylethylenediamine
Ferrocene
Chlorodiphenylphosphine
Phenyllithium
Ethyl acetate
n-Butyllithium
N,N,N',N'-Tetramethylethylenediamine
Ferrocene
Chlorodiphenylphosphine
Phenyllithium
Downstream Products for 1,1-bis(diphenyphosphino)ferrocene
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
N,N'-Bis- (1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)-4,4'-diamine
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
N,N'-Bis- (1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)-4,4'-diamine
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)