1-Bromohexane
1-Bromohexane
CAS: 111-25-1
Molecular Formula: C6H13Br
1-Bromohexane - Names and Identifiers
| Name | 1-Bromohexane |
| Synonyms | Bromohexane N-BROMOHEXANE 1-Bromohexane 1-bromo-hexan 1-BROMOHEXANE HEXYL BROMIDE 1-hexylbromide N-HEXYL BROMIDE n-Hexyl bromide 1-Hexyl bromide |
| CAS | 111-25-1 |
| EINECS | 203-850-2 |
| InChI | InChI=1/C6H13Br/c1-2-3-4-5-6-7/h2-6H2,1H3 |
| InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
1-Bromohexane - Physico-chemical Properties
| Molecular Formula | C6H13Br |
| Molar Mass | 165.07 |
| Density | 1.176g/mLat 25°C(lit.) |
| Melting Point | −85°C(lit.) |
| Boling Point | 154-158°C(lit.) |
| Flash Point | 135°F |
| Water Solubility | Immiscible with water. |
| Vapor Presure | <10 mm Hg ( 20 °C) |
| Vapor Density | 5.7 (vs air) |
| Appearance | Liquid |
| Color | Clear |
| BRN | 1731290 |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
| Refractive Index | n20/D 1.448(lit.) |
| Physical and Chemical Properties | Density 1.176 melting point -85°C boiling point 154-158°C refractive index 1.4465-1.4485 flash point 57°C |
| Use | Used as a solvent, but also for organic synthesis |
1-Bromohexane - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R10 - Flammable |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S16 - Keep away from sources of ignition. |
| UN IDs | UN 1993 3/PG 3 |
| WGK Germany | 2 |
| RTECS | MO0925000 |
| TSCA | Yes |
| HS Code | 29033036 |
| Hazard Class | 3 |
| Packing Group | III |
| Toxicity | LD50 orally in Rabbit: > 2000 mg/kg |
1-Bromohexane - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| use | solvent, organic synthesis. Used as a solvent and also used in organic synthesis |
| production method | 16g(0.1mol) of bromine is dissolved in 50mL of carbon tetrachloride, and slowly and gradually added to 13g(0.1mol) heptanoic acid and 22g(0.0945m mercury chloride and 150mL of dry carbon tetrachloride solution under stirring. The reflux filtrate of the mixture is washed with 5% NaOH solution, then washed with water, and anhydrous sulfur night. Fractionated 6g(36%)1-bromohexane,. |
| category | flammable liquid |
| toxicity classification | poisoning |
| acute toxicity | abdominal injection-mouse LD50: 1226 mg/kg |
| flammability hazard characteristics | combustible in case of open flame, high temperature and strong oxidant; Thermal decomposition of toxic hydrogen bromide gas |
| storage and transportation characteristics | complete packaging, light and light; warehouse ventilation, away from open flames, high temperature, separate from oxidant and strong acid |
| fire extinguishing agent | foam, carbon dioxide, dry powder, sand, mist water |
| occupational standard | STEL 0.3 mg/m3 |
Last Update：2024-04-09 20:52:54
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