105029-70-7

105029-70-7 - Names and Identifiers

Name	Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(Iii) Complex
Synonyms	Tetrabutylphosphonium Bis(1,3-dithiole-2-thione-4,5-dithiolato)nickel(III) Complex Tetrabutylphosphonium Bis(4,5-dimercapto-1,3-dithiol-2-thionato-S4,S5)niccolate(Ⅲ) Tetrabutylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(Iii) Complex Tetrabutylphosphonium Bis(4,5-Dimercapto-1,3-Dithiol-2-Thionato-S4,S5)Niccolate(Iii) TETRABUTYLPHOSPHONIUM BIS(4,5-DIMERCAPTO-1,3-DITHIOL-2-THIONATO-S4,S5)NICCOLATE(III) Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)- Nickel(3) Complex TETRA-N-BUTYLPHOSPHONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)NICKEL(III) COMPLEX Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(Iii) Complex TETRA-N-BUTYLPHOSPHONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)- NICKEL(3) COMPLEX
CAS	105029-70-7
InChI	InChI=1/C16H36P.2C3H2S5.Ni/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;24-1-2(5)8-3(6)7-1;/h5-16H2,1-4H3;24-5H;/q+1;;;+3/p-4/rC16H36P.C6NiS10/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;8-5-10-1-2(11-5)15-7(14-1)16-3-4(17-7)13-6(9)12-3/h5-16H2,1-4H3;/q+1;-1

105029-70-7 - Physico-chemical Properties

Molecular Formula	C22H40NiPS10
Molar Mass	714.83
Appearance	powder to crystal
Color	Dark green to Dark blue to Black
Storage Condition	2-8℃
MDL	MFCD00191494

105029-70-7 - Introduction

Tetrabutylphosphonium bis (1,3-dithiacyclopentadiene-2-thione-4, 5-dithiol) nickel (III) is a coordination compound with the following properties:

1. Appearance: Tetrabutylphosphonium bis (1,3-dithiacyclopentadiene -2-thione-4, 5-dithiol) nickel (III) is a solid, usually yellow or orange powder.

2. Thermal stability: The compound is relatively stable at high temperatures and can maintain structural integrity within a certain range.

3. Solubility: tetrabutyl phosphonium bis (1,3-dithiacyclopentadiene -2-thione -4,5-dithiol) nickel (III) has high relative solubility in organic solvents, such as diethyl ether, chloroform, etc.

The main uses of tetrabutylphosphonium bis (1,3-dithiacyclopentadiene -2-thione-4, 5-dithiol) nickel (III) are as follows:

1. Catalyst: The coordination compound can be used as a catalyst to participate in organic synthesis reactions and promote chemical reactions.

2. Electrochemical applications: The compound can be used as an electrochemical catalyst, such as for oxygen reduction reaction in fuel cells.

the preparation method of tetrabutylphosphonium bis (1,3-dithiacyclopentadiene -2-thione-4, 5-dithiol) nickel (III) is generally obtained by coordination reaction, the specific steps are as follows:

1. An appropriate amount of 1,3-dithiacyclopentadiene -2-thione-4, 5-dithiol is reacted with tetrabutylphosphonium, heated and stirred in a solvent.

2. Add the appropriate amount of nickel (III) chloride and continue to stir the reaction.

3. After the reaction is completed, filtration or centrifugation is performed to obtain tetrabutylphosphonium bis (1,3-dithiacyclopentadiene -2-thione-4, 5-dithiol) nickel (III) in the form of yellow or orange powder.

Regarding safety information, no information is available on the specific toxicity and danger of tetrabutylphosphonium bis (1,3-dicyclopentadiene -2-thione-4, 5-dithiol) nickel (III). However, any chemical should follow basic laboratory safety procedures, properly wear personal protective equipment, avoid contact with skin, eyes or respiratory tract, avoid inhaling its dust, and avoid long-term contact. In the use and handling of chemicals, appropriate precautions should be followed and waste should be properly managed. During use, if symptoms of discomfort or poisoning occur, medical help should be sought.

Last Update：2024-04-09 20:02:46