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12112-67-3

Chloro(1,5-cyclooctadiene)iridium(I) dimer

CAS: 12112-67-3

Molecular Formula: C16H24Cl2Ir2

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12112-67-3 - Names and Identifiers

Name Chloro(1,5-cyclooctadiene)iridium(I) dimer
Synonyms IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
IRIDIUM I CYCLOOCTADIENE CHLORIDE
Chloro-1,5-cyclooctadiene iridium(I) dimer
Chloro(1,5-cyclooctadiene)iridium(I) dimer
CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER
CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER
BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE
IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER
DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)]
1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt
DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM
CAS 12112-67-3
EINECS 235-170-7
InChI InChI=1/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;;
InChIKey XHOSESNLNGITPM-XRGHXPOKSA-L

12112-67-3 - Physico-chemical Properties

Molecular FormulaC16H24Cl2Ir2
Molar Mass671.7
Melting Point205°C (dec.)(lit.)
Boling Point153.5°C at 760 mmHg
Flash Point31.7°C
Water Solubilityinsoluble
Vapor Presure4.25mmHg at 25°C
AppearanceRed-orange powder
Colorred to orange
Storage ConditionKeep in dark place,Inert atmosphere,2-8°C
Sensitive7: reacts slowly with moisture/water
MDLMFCD00012414

12112-67-3 - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 - Wear suitable gloves and eye/face protection
WGK Germany3
FLUKA BRAND F CODES10
TSCANo
HS Code28439000

12112-67-3 - Introduction

A metal precursor for asymmetric allylic substitutions.
Last Update：2022-10-16 17:12:45

12112-67-3 - Reference Information

Use 1,5-cyclooctadiene iridium chloride dimer is iridium catalyzed by iridium for the asymmetric hydrogenation of unfunctionalized extracyclic double carbon bonds catalyst. In addition, it is also used to test new opox ligands from serine or threonine.
1, 5-cyclooctadiene iridium chloride dimer is an organic precious metal catalyst, used for the asymmetric hydrogenation reaction of non-functionalized outer ring double carbon bonds catalyzed by iridium. At the same time, it is also used to test new Neo phosphorus ligands, which are derived from serine or threonine.
Last Update：2024-04-10 22:29:15
12112-67-3
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Tel: 18301782025
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View History
12112-67-3
1436-34-6
1271-19-8
99853-96-0
Iridium
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