131614-43-2

131614-43-2 - Names and Identifiers

Name	Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Synonyms	RuCl(p-cymene)((R)-tolbinap) (R)-RuCl[(p-cymene)(T-BINAP)]Cl Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane 1-[2-(bis-p-tolylphosphanyl)-1-naphthyl]-2-naphthyl]-bis(p-tolyl )phosphane, dichlororuthenium, 1-isopropyl-4-methyl-benzene Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-tolbinap)]Cl
CAS	131614-43-2
InChI	InChI=1/C48H40P2.C10H14.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-8(2)10-6-4-9(3)5-7-10;;;/h5-32H,1-4H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

131614-43-2 - Physico-chemical Properties

Molecular Formula	[C58H54ClP2Ru]+Cl-
Molar Mass	984.97
Melting Point	>100°C
Appearance	Powder
Color	brown
Storage Condition	2-8°C
Sensitive	air sensitive

131614-43-2 - Introduction

Chloro [(R)-(+)-2,2 '-bis (bis-p-phenylphosphino)-1,1'-binaphthyl](p-cymene) ruthenium (II) chloride, abbreviated as [R-DV-chloro][BPh4]RuCl, is a chiral organometallic compound.

Nature:
-Appearance: colorless crystal
-Solubility: Soluble in some organic solvents, such as methanol and acetonitrile
-Thermal stability: stable at high temperatures
-Optical properties: with good fluorescence properties

Use:
[R-DV-chloro][BPh4]RuCl has a wide range of applications in photoelectrochemical and fluorescence studies. It can be used as a key component of photoluminescent materials and photoelectric conversion devices. It can also be used in fields such as organic light emitting diodes (OLED), liquid crystal displays, and solar cells.

Preparation Method:
[R-DV-chloro][BPh4]RuCl is generally prepared by metal organic chemical synthesis methods. A common preparation method is to react [R-DV-chloro][BPh4]RuCl with an appropriate amount of ruthenium (II) chloride, and then purify the final product by crystallization.

Safety Information:
The compound is generally relatively safe under proper handling and storage conditions. However, since it is a metal organic compound, contact with open flames and oxygen should be avoided to prevent possible fire and explosion. At the same time, care should be taken to avoid inhalation and contact with skin or eyes during use to avoid potential health risks. In use, follow appropriate laboratory safety practices and use appropriate personal protective equipment.

Last Update：2024-04-09 21:11:58