14264-16-5
Bis(triphenylphosphine)nickel(II)chloride
CAS: 14264-16-5
Molecular Formula: C36H30Cl2NiP2
14264-16-5 - Names and Identifiers
| Name | Bis(triphenylphosphine)nickel(II)chloride |
| Synonyms | dichloronickel triphenylphosphonium Bis(triphenylphosphine)nick Dichlorobis(triphenyIphosphine)-nickel Bis(tri-N-butylphosphine)dichloronickel Dichlorobis(triphenylphosphine)nickel(Ⅱ) Dichlorobis(triphenylphosphine)nickel(II) Bis(triphenylphosphine)nickel(II)chloride Nickel(II) chloride bis(triphenylphosphine) Bis(triphenylphosphine)nickel(II)dichloride [Bis(triphenylphosphine)]dichloroNickel(II) tributyl-phosphin compd. with nickelchloride Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride |
| CAS | 14264-16-5 |
| EINECS | 238-154-8 |
| InChI | InChI=1/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2 |
14264-16-5 - Physico-chemical Properties
| Molecular Formula | C36H30Cl2NiP2 |
| Molar Mass | 654.17 |
| Melting Point | 250°C (dec.)(lit.) |
| Water Solubility | insoluble |
| Solubility | DMSO (Slightly), Methanol (Slightly) |
| Appearance | Crystals or Powder |
| Color | Dark green to dark gray |
| Exposure Limit | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Storage Condition | Inert atmosphere,Room Temperature |
| Sensitive | Hygroscopic |
| Physical and Chemical Properties | Melting point 250°C (dec.) water-soluble insoluble |
14264-16-5 - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | R45 - May cause cancer R43 - May cause sensitization by skin contact R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R34 - Causes burns R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | S53 - Avoid exposure - obtain special instructions before use. S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | 3260 |
| WGK Germany | 3 |
| RTECS | QR6170000 |
| FLUKA BRAND F CODES | 21 |
| TSCA | Yes |
| HS Code | 29310095 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
14264-16-5 - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | catalyst in the coupling reaction of aryl methanesulfonyl salt, allyl carbonate and organic lithium borate. |
| category | toxic substances |
| toxicity grade | high toxicity |
| Acute toxicity | intravenous-mouse LD50: 56 mg/kg |
| flammability hazard characteristics | thermal decomposition of toxic sulfur oxide gases |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; Stored separately from oxidants and acids |
| extinguishing agent | water, dry powder, dry sand, carbon dioxide, foam, 1211 extinguishing agent |
| Occupational Standard | TWA 0.1 mg (tin)/m3 (skin); PEL 0.2 mg (tin)/M3 (skin) |
Last Update：2024-04-10 22:29:15
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