162291-02-3
(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine
CAS: 162291-02-3
Molecular Formula: C36H44FeP210*
162291-02-3 - Names and Identifiers
| Name | (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine |
| Synonyms | (S)-(R)-Josiphos JOSIPHOS SL-J001-2 (S)1[(1R)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos (S)-1-[(1R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine (S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenylethyl]dicyclohexylphosphine (2S)-1-[(1S)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene cyclopentane,dicyclohexyl-[(1S)-1-(2-diphenylphosphanylcyclopentyl)ethyl]phosphane,iron (S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct (S)-(R)-JOSIPHOS |
| CAS | 162291-02-3 |
| InChI | InChI=1/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m0../s1 |
162291-02-3 - Physico-chemical Properties
| Molecular Formula | C36H44FeP210* |
| Molar Mass | 594.53 |
| Specific Rotation(α) | +360° (c 0.5, CHCl3) |
| Appearance | Powder |
| Color | orange |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Stability | store cold |
| MDL | MFCD00800285 |
162291-02-3 - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10 |
| HS Code | 29319090 |
162291-02-3 - Preparation solution concentration reference
| 1mg | 5mg | 10mg | |
|---|---|---|---|
| 1 mM | 1.682 ml | 8.41 ml | 16.82 ml |
| 5 mM | 0.336 ml | 1.682 ml | 3.364 ml |
| 10 mM | 0.168 ml | 0.841 ml | 1.682 ml |
| 5 mM | 0.034 ml | 0.168 ml | 0.336 ml |
Last Update：2024-01-02 23:10:35
162291-02-3 - Reference Information
| Use | (S)-( )-1-[(R)-2-(diphenylphosphine) ferrocene] ethyl dicyclic hexylphosphine is a kind of Josiphos chiral ferrocene phosphine ligand, is a very practical and important ligand, its pioneering is second only to BINAP ligand, it can be used in asymmetric organic synthesis reactions such as asymmetric hydroamination of olefins and Michael addition. It has been widely used in industrial production and plays an important role in the synthesis of many drugs and fine chemicals. |
Last Update：2024-04-10 22:29:15
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