17185-29-4
Carbonyltris(triphenylphosphine)rhodium(I)
CAS: 17185-29-4
Molecular Formula: 3C18H15P.CO.HRh
17185-29-4 - Names and Identifiers
| Name | Carbonyltris(triphenylphosphine)rhodium(I) |
| Synonyms | carbon monoxide (betab-5-23)-rhodiu Carbonyltris(triphenylphosphine)rhodium(I) carbonylhydrotris(triphenylphosphine)rhodium Carbonyl hydridotris(triphenylphosphine) rhodium Carbonylhydridotris(triphenylphosphine)rhodium(I) Carbonyltris(triphenylphosphine)rhodium(I)hydride CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Hydridocarbonyltris(triphenylphosphine)rhodium(I) Carbonylhydridotris(triphenylphosphine)rhodium(Ⅰ) CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I) Carbonyltris(triphenylphosphine)rhodium(I) hydride TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE |
| CAS | 17185-29-4 |
| EINECS | 241-230-3 |
| InChI | InChI=1/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;;/r3C18H15P.CO.HRh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h3*1-15H;;1H |
| InChIKey | CEKFIOLKXHVOKA-UHFFFAOYSA-N |
17185-29-4 - Physico-chemical Properties
| Molecular Formula | 3C18H15P.CO.HRh |
| Molar Mass | 918.8 |
| Density | 1.33 |
| Melting Point | 150 °C (dec.) (lit.) |
| Boling Point | 360℃ at 760mmHg |
| Solubility | Insoluble in water. Soluble in hydrocarbons (such as benzene, toluene, etc.), accompanied by dissociation of the phosphine ligand. |
| Vapor Presure | 0Pa at 25℃ |
| Appearance | Yellow powder |
| Color | light yellow |
| Exposure Limit | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Merck | 14,9758 |
| Storage Condition | Keep in dark place,Inert atmosphere,2-8°C |
| Sensitive | Moisture Sensitive |
| MDL | MFCD00151644 |
| Use | Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation and other reactions. |
17185-29-4 - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | 23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37 - Wear suitable protective clothing and gloves. |
| UN IDs | UN 2811 6.1/PG 2 |
| WGK Germany | 1 |
| FLUKA BRAND F CODES | 10-23 |
| TSCA | Yes |
| HS Code | 28439000 |
| Hazard Class | 4.3 |
| Packing Group | III |
17185-29-4 - Introduction
Insoluble in water. Soluble in hydrocarbons (such as benzene, toluene, etc.), accompanied by dissociation of the phosphine ligand. Sensitive to air and humidity.
Last Update：2022-10-16 17:14:24
17185-29-4 - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| Use | Used for olefin isomerization, hydroformylation Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, Oxidation and other reactions. |
Last Update：2024-04-10 22:29:15
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