199541-17-8

199541-17-8 - Names and Identifiers

Name	Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms	-Cl)3][NH2Me2] [NH2ME2][(RUCL((S)-BINAP))2(Μ-CL)3] (S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2] (S)-[(RuCl(BINAP))2(mu-Cl)3][NH2Me2] [NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3] -binaphthyl]diruthenate(II),[NH2Me2][{RuCl((S) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II) DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((S)
CAS	199541-17-8

199541-17-8 - Physico-chemical Properties

Molecular Formula	2C44H32P2.C2H7N.Cl.Cl3Ru2.ClH
Molar Mass	1670.87
Melting Point	>100°C
Water Solubility	Insoluble in water
Appearance	Powder
Color	orange
Storage Condition	2-8°C
Sensitive	air sensitive

199541-17-8 - Risk and Safety

Hazard Symbols	F - Flammable
Risk Codes	11 - Highly Flammable
UN IDs	UN 1325 4.1/PG 3
WGK Germany	3

199541-17-8 - Introduction

(mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) is an organometallic compound, the chemical formula is [CpCl(PPh2) 2rucl2]. It has the following properties:

1. Appearance and properties: (mu-chloro)bis[(S)-(-)-2,2 '-bis (diphenylphino)-1,1'-binaphthyl]diruthenate(II) it is a yellow crystal with a special structure.

2. Stability: it is relatively stable in dry air, but easy to damp, should be stored in a dry environment. Avoid direct sunlight and high temperatures.

3. Solubility: (mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl] diruthiate (II) soluble in many organic solvents, such as ether, chloroform and methanol.

(mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl diruthenate(II) the main uses are as follows:

1. Catalyst: It can be used as a catalyst in organic synthesis reactions, such as asymmetric carbene reaction, olefin cyclization reaction and asymmetric hydrogenation reaction.

2. Metal organic chemistry research: It can be used in metal organic chemistry research, such as the preparation of other metal organic compounds and the study of metal organic reaction mechanisms.

3. Photovoltaic materials: (mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl diruthenate(II) and its derivatives have potential applications in the field of photovoltaic materials.

Preparation of mu-chloro bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) the method is as follows:

First, combine [RuCl2(PPh3)3](triphenylphosphine rhenium chloride (II)) with ()-BIS [(S)-Piperidine-2-methylene]-2-binaphthyl alcohol is reacted to give [CpCl(PPh2) 2rucl2].

About (mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) safety information:

1. (mu-chloro)bis[(S)-(-)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) is a chemical, keep away from ignition and heat sources.

2. Avoid contact with skin and eyes during use. If you accidentally touch, please rinse with plenty of water immediately and seek medical assistance.

3. Storage should be kept in a sealed container, away from acids, alkalis and oxidants.

4. Wear appropriate personal protective equipment during operation, such as laboratory gloves, protective glasses and laboratory coats.

These are all about 2 mu-chloro bis[(S)-(-)-, 2 '-bis(diphenylphosphino)-1,1'-binaphthyl] dirutenate (II) information about the nature, use, preparation and safety information.

Last Update：2024-04-10 22:29:15