220114-03-4
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
CAS: 220114-03-4
Molecular Formula: C66H64Cl2N2P2Ru
220114-03-4 - Names and Identifiers
220114-03-4 - Physico-chemical Properties
| Molecular Formula | C66H64Cl2N2P2Ru |
| Molar Mass | 1119.15 |
| Appearance | Powder |
| Color | yellow |
| Storage Condition | 2-8°C |
| Sensitive | air sensitive |
220114-03-4 - Risk and Safety
| WGK Germany | 3 |
220114-03-4 - Introduction
Dichloro{(S)-(-)-2,2 '-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) is an organometallic complex with the chemical formula Cl {(S)-(-)-BINAP}[(1S,2S)-(-)-DPEN]Ru(II), where BINAP is 2,2 '-BIS [BIS (3,5-xylyl) phosphine]-1,1'-Binaphthyl, DPEN is 1,2-diphenylethylenediamine.
The properties of this complex are as follows:
1. Appearance: colorless crystal or white powder;
2. Solubility: soluble in common organic solvents (such as dichloromethane, toluene, etc.);
3. Melting Point: about 100-110 ℃.
This complex has important applications in chemical synthesis and catalytic reactions:
1. As a catalyst: can be used in various organic synthesis reactions, such as asymmetric hydrogenation and disproportionation reactions;
2. Electrochemical application: can be used for asymmetric electrosynthesis reaction, electrochemical synthesis, etc.
The method of preparing the complex is obtained by the reaction of the ligand and the metal salt:
1. The ligands BINAP and DPEN react with metal salts of ruthenium (II) to form complexes.
Regarding the safety information of the substance, because the chemical substance has a certain degree of danger, the following matters should be paid attention to when handling:
1. Avoid direct contact with skin, eyes and respiratory tract, and avoid inhaling dust;
2. In the operation should wear personal protective equipment, such as gloves, goggles and gas masks, etc;
3. It is best to conduct the experiment in a well-ventilated laboratory to avoid toxic gases or volatiles.
Please note that when using or handling this compound, it is important to follow local safety practices and refer to the safety data sheet for the relevant chemical and the safety information provided by the supplier.
The properties of this complex are as follows:
1. Appearance: colorless crystal or white powder;
2. Solubility: soluble in common organic solvents (such as dichloromethane, toluene, etc.);
3. Melting Point: about 100-110 ℃.
This complex has important applications in chemical synthesis and catalytic reactions:
1. As a catalyst: can be used in various organic synthesis reactions, such as asymmetric hydrogenation and disproportionation reactions;
2. Electrochemical application: can be used for asymmetric electrosynthesis reaction, electrochemical synthesis, etc.
The method of preparing the complex is obtained by the reaction of the ligand and the metal salt:
1. The ligands BINAP and DPEN react with metal salts of ruthenium (II) to form complexes.
Regarding the safety information of the substance, because the chemical substance has a certain degree of danger, the following matters should be paid attention to when handling:
1. Avoid direct contact with skin, eyes and respiratory tract, and avoid inhaling dust;
2. In the operation should wear personal protective equipment, such as gloves, goggles and gas masks, etc;
3. It is best to conduct the experiment in a well-ventilated laboratory to avoid toxic gases or volatiles.
Please note that when using or handling this compound, it is important to follow local safety practices and refer to the safety data sheet for the relevant chemical and the safety information provided by the supplier.
Last Update：2024-04-10 22:29:15
Supplier List
Spot supply
Product Name: Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Request for quotationCAS: 220114-03-4
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365
Wechat: 18916960931
Spot supply
Product Name: RuCl2[(S)-xylbinap][(S,S)-dpen] Visit Supplier Webpage Request for quotationCAS: 220114-03-4
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Visit Supplier Webpage Request for quotationCAS: 220114-03-4
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Request for quotationCAS: 220114-03-4
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365
Wechat: 18916960931
Spot supply
Product Name: RuCl2[(S)-xylbinap][(S,S)-dpen] Visit Supplier Webpage Request for quotationCAS: 220114-03-4
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Visit Supplier Webpage Request for quotationCAS: 220114-03-4
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
View History