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436863-50-2

1,1′-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene

CAS: 436863-50-2

Molecular Formula: C26H40FeP2

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436863-50-2 - Names and Identifiers

Name 1,1′-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene
Synonyms S,S-Et-Ferrocelane
1,1′-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene
1,1'-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ferrocene
carbanide,(2S,5S)-1-cyclopentyl-2,5-diethylphospholane,iron(2+)
CAS 436863-50-2

436863-50-2 - Physico-chemical Properties

Molecular FormulaC26H40FeP2
Molar Mass470.39
Melting Point89-91°C
Appearancesolid
Coloryellow
Storage Conditionunder inert gas (nitrogen or Argon) at 2-8°C
Sensitiveair sensitive
Physical and Chemical PropertiesOptical rotation (optical activity) [α]20/D -382 °, c = 1 in chloroform

436863-50-2 - Risk and Safety

WGK Germany3

436863-50-2 - Introduction

1,1 '-BIS [(2S,5S)-2,5-diethylphosphinoalkyl] Ferrocene is an organic compound with the molecular formula C26H38FeP2 and a molecular weight of 503.38. It is a dark red crystal, soluble in some organic solvents, such as toluene and methylene chloride.

The main use of this compound is as a chiral catalyst for asymmetric catalysis in organic synthesis reactions. It is widely used in asymmetric hydrogenation, Asymmetric oxidation, asymmetric hydroxyamide synthesis and other reactions. Its chiral structure can make the enantioselectivity better, which is helpful for the synthesis of chiral molecules.

1,1 '-BIS [(2S,5S)-2,5-diethylphosphinoalkyl] Ferrocene is usually prepared by mixing 2, the 5-diethylphosphinoalkanol is obtained by reaction with sodium Di (ferrocene) dimethyl. After this step, the target product can be obtained by acid treatment and crystallization purification.

When using and handling 1,1 '-BIS [(2S,5S)-2,5-diethylphosphinoalkyl] ferrocene, safety precautions should be paid attention. It is an organic compound and should avoid violent reactions with strong oxidants and strong acids. Care should be taken to prevent inhalation, ingestion or contact with skin. Wear appropriate protective equipment, such as gloves, glasses and protective clothing, if necessary.

In General, 1,1 '-BIS [(2S,5S)-2,5-diethylphosphinoalkyl] ferrocene has important catalytic applications, especially for the synthesis of chiral compounds. However, it is necessary to pay attention to safe operation during use.
Last Update:2024-04-10 22:29:15
436863-50-2
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Shanghai Amole Biotechnology Co., Ltd.
Spot supply
Product Name: 1,1-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene Request for quotation
CAS: 436863-50-2
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365 Click to send a QQ message
Wechat: 18916960931
Shanghai Macklin Biochemical Co., Ltd
Spot supply
Product Name: 1,1-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene Visit Supplier Webpage Request for quotation
CAS: 436863-50-2
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
WhatsApp: +86-18821248368
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: 1,1-Bis[(2S,5S)-2,5-diethylphospholano]ferrocene Visit Supplier Webpage Request for quotation
CAS: 436863-50-2
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
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