446866-87-1
3-Morpholinobenzaldehyde
CAS: 446866-87-1
Molecular Formula: C11H13NO2
446866-87-1 - Names and Identifiers
| Name | 3-Morpholinobenzaldehyde |
| Synonyms | 3-MORPHOLINOBENZALDEHYDE 3-Morpholinobenzaldehyde 4-(3-Formylphenyl)morpholine 3-(4-morpholinyl)benzaldehyde 3-MORPHOLIN-4-YL-BENZALDEHYDE 3-(Morpholin-4-yl)benzaldehyde Benzaldehyde, 3-(4-morpholinyl)- |
| CAS | 446866-87-1 |
| InChI | InChI=1/C11H13NO2/c13-9-10-2-1-3-11(8-10)12-4-6-14-7-5-12/h1-3,8-9H,4-7H2 |
446866-87-1 - Physico-chemical Properties
| Molecular Formula | C11H13NO2 |
| Molar Mass | 191.23 |
| Density | 1.163±0.06 g/cm3(Predicted) |
| Melting Point | 68 °C |
| Boling Point | 357.9±37.0 °C(Predicted) |
| Flash Point | 170.3°C |
| Vapor Presure | 2.64E-05mmHg at 25°C |
| pKa | 3.80±0.40(Predicted) |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Refractive Index | 1.581 |
446866-87-1 - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R21/22 - Harmful in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S22 - Do not breathe dust. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| Hazard Note | Harmful |
446866-87-1 - Reference Information
| use | 3-morpholinyl benzaldehyde can be used as an intermediate in pharmaceutical synthesis. |
| preparation | 3-bromobenzaldehyde (6.44g,35.0mmol,1.00 equivalent), morpholine (9.13g,105mmol,3.00 equivalent), tris (dibenzylidene acetone) dipalladium (1.81g, 1.75 mmol, 0.05 equivalent), dicyclohexyl (2 ',6'-diisopropoxybiphenyl-2-yl) phosphine (3.26g, 7.00 mmol, 0.20 equivalent), cesium carbonate (34.2g,105mmol) under nitrogen, 3.00 equivalent), toluene (100mL). The resulting solution was stirred overnight at 90°C and quenched with water (50mL). The resulting solution was extracted with dichloromethane (3 × 200mL), the organic layers were combined, washed with brine (3 × 100mL), dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The residue was chromatographically separated on silica gel column with ethyl acetate/petroleum ether (3/17) to obtain 3-morpholinyl benzaldehyde (2.10g,32% yield), which was yellow oil. |
Last Update：2024-04-10 22:29:15
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446866-87-1
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139428-96-9
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琥珀酸酣 AR
101018-70-6
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2285351-50-8
38076-80-1
35109-88-7
107233-58-9
139428-96-9
153355-70-5
琥珀酸酣 AR
101018-70-6
136030-00-7