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540475-45-4

1,1-Bis((2R,5R)-2,5-Dimethylphospholano)Ferrocene

CAS: 540475-45-4

Molecular Formula: C22H32FeP2

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540475-45-4 - Names and Identifiers

Name 1,1-Bis((2R,5R)-2,5-Dimethylphospholano)Ferrocene
Synonyms R,R-Me-Ferrocelane
(2r,5r)-1-cyclopentyl-2,5-dimethylphospholane
1,1-Bis((2R,5R)-2,5-Dimethylphospholano)Ferrocene
1,1'-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ferrocene
(+)-1,1'-Bis[(2R,5R)-2,5-dimethylphospholano]ferrocene
CAS 540475-45-4

540475-45-4 - Physico-chemical Properties

Molecular FormulaC22H32FeP2
Molar Mass414.28
Melting Point99-102℃
Water SolubilityInsoluble in water.
Appearancesolid
Coloryellow
Storage Conditionunder inert gas (nitrogen or Argon) at 2-8°C
SensitiveAir Sensitive

540475-45-4 - Risk and Safety

WGK Germany3

540475-45-4 - Introduction

1,1-bis ((2R,5R)-2,5-dimethylphosphoric acid) Ferrocene is an organometallic compound with the molecular formula C18H24FeP2 and a molecular weight of 378.22g/mol.

Nature:
1,1-bis ((2R,5R)-2,5-dimethylphosphoric acid) Ferrocene is a yellow crystal or crystal powder. It is insoluble in water at room temperature, but soluble in some organic solvents such as methanol and ethanol. Its melting point is 205-206 ° C.

Use:
1,1-bis ((2R,5R)-2,5-dimethylphosphate) Ferrocene is a commonly used chiral ligand, which can be used for asymmetric catalysis in organic synthesis reactions. It acts as a catalyst in many important organic synthesis reactions, such as asymmetric hydrogenation and carbonyl reduction. In addition, it can also be used as a material in the field of gas separation and storage.

Method:
A commonly used method for preparing 1,1-bis ((2R,5R)-2,5-dimethylphosphoric acid) Ferrocene is to first pass [Fe(η5-C5H5)2Cl]2 reacts with the corresponding ligand 2R,5R-dimethylphosphoric acid to obtain the intermediate [(η5-C5H5)Fe(η5-2R,5R-dimethylphosphoric acid)], which is reduced with NaBH4, the final product is obtained.

Safety Information:
1,1-bis ((2R,5R)-2,5-dimethylphosphoric acid) ferrocene has high safety, but some safety measures still need to be paid attention. During use, it should be kept away from fire and high temperature, and should be sealed and stored to avoid direct sunlight. Wear appropriate protective equipment such as lab gloves and goggles during operation. If it comes into contact with skin or eyes, rinse immediately with plenty of water and consult a doctor.
Last Update:2024-04-10 22:29:15
540475-45-4
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Shanghai Amole Biotechnology Co., Ltd.
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CAS: 540475-45-4
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Shanghai Amole Biotechnology Co., Ltd.
Spot supply
Product Name: 1,1-Bis((2R,5R)-2,5-dimethylphospholano)ferrocene Request for quotation
CAS: 540475-45-4
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365 Click to send a QQ message
Wechat: 18916960931
Shanghai Macklin Biochemical Co., Ltd
Spot supply
Product Name: 1,1-Bis((2R,5R)-2,5-dimethylphospholano)ferrocene Visit Supplier Webpage Request for quotation
CAS: 540475-45-4
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
WhatsApp: +86-18821248368
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: 1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97% Visit Supplier Webpage Request for quotation
CAS: 540475-45-4
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
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