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5666-12-6

tris(1-pyrrolidinyl)phosphine

CAS: 5666-12-6

Molecular Formula: C12H24N3P

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5666-12-6 - Names and Identifiers

Name tris(1-pyrrolidinyl)phosphine
Synonyms Tripyrrolidinophosphine
Tris(pyrrolidino)phosphine
Tri(1-pyrrolidinyl)phosphine
Tri(pyrrolidin-1-yl)phosphane
Tris(N-pyrrolidinyl)phosphine
tris(1-pyrrolidinyl)phosphine
phosphorous acid tripyrrolidide
TRIS(1-PYRROLIDINYL)PHOSPHINE 97
CAS 5666-12-6

5666-12-6 - Physico-chemical Properties

Molecular FormulaC12H24N3P
Molar Mass241.31
Density1.041 at 25 °C1.049 g/mL at 25 °C (lit.)
Boling Point104 °C/0.1 mmHg (lit.)
Flash Point>230°F
BRN1343311
pKa9.74±0.20(Predicted)
Storage Conditionunder inert gas (nitrogen or Argon) at 2-8°C
Refractive Indexn20/D 1.53(lit.)

5666-12-6 - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
WGK Germany3

5666-12-6 - Introduction

tris(1-pyrrolidinyl)phosphine is an organophosphorus compound with the chemical formula C15H27NP. It is a white crystalline solid which is soluble in common organic solvents such as methanol, dimethylformamide and dichloromethane.

Tris (1-Pyrrolidinyl) phosphine are widely used as catalysts and ligands, and have a wide range of applications. It is often used in catalytic hydrogenation, addition reaction and reduction reaction in organic synthesis. In addition, it can also be used as a catalyst for negative ion polymerization, plastic synthesis and organic metal catalytic reactions.

A common method for preparing tris(1-pyrrolidinyl)phosphine is by the reaction of phenylchlorophosphine and pyrrolidine. The process needs to be carried out under the protection of inert gas to prevent the influence of oxygen and moisture.

Regarding safety information, tris(1-pyrrolidinyl)phosphine is relatively safe under correct use and storage. However, it is a combustible substance and should be kept away from open flames and high temperatures. It is necessary to avoid inhaling its gas or direct contact with the skin during operation. If inhaled or exposed, rinse immediately with clean water and seek medical help if necessary.

It is worth noting that for the use and handling of any chemical, the safety operation manual and instructions for the chemical should be carefully read and followed, and the laboratory safety regulations should be followed.
Last Update:2024-04-10 22:29:15
5666-12-6
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CAS: 5666-12-6
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