95464-05-4
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
CAS: 95464-05-4
Molecular Formula: C35H24Cl4FeP2Pd
95464-05-4 - Names and Identifiers
95464-05-4 - Physico-chemical Properties
| Molecular Formula | C35H24Cl4FeP2Pd |
| Molar Mass | 810.59 |
| Density | 1 g/cm3 |
| Melting Point | 275-280°C(lit.) |
| Water Solubility | Insoluble in water. |
| Solubility | Chloroform (Slightly), Methanol (Slightly) |
| Appearance | orange/red solid |
| Color | orange-red |
| Storage Condition | Keep in dark place,Inert atmosphere,Room temperature |
| Stability | Light Sensitive |
| MDL | MFCD00015757 |
| Use | Applied to palladium-catalyzed cross-coupling reactions |
95464-05-4 - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect R67 - Vapors may cause drowsiness and dizziness R48/20/22 - |
| Safety Description | S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves. |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
95464-05-4 - Introduction
This product is useful for the borylation of triflate with pinacolborane.
Last Update：2022-10-16 17:30:21
95464-05-4 - Reference Information
| Introduction | various phosphine Bridge transition binuclear complexes with bidentate phosphine ligands are mainly due to their special structure, because of its novel catalytic properties, ferrocene has attracted much attention due to its special molecular structure. 1,1 '-bis (diphenylphosphine) ferrocene (dppf) is a novel ligand that combines organic bidentate phosphine ligands with ferrocene, A wide variety of bimetallic and multimetallic complexes can be formed with another transition metal atom. |
| Application | [1,1 '-bis (diphenylphosphino) ferrocene] Palladium dichloride methylene chloride complex is an organometallic compound, it can be used as a noble metal catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction. |
| preparation | Step 1: dissolve 2.00g of sodium chloropalladium in 30ml of absolute ethanol, step 2: dissolve 4.15G of 1,1 '-bis (diphenylphosphine) ferrocene in 41ml of dichloromethane to obtain 1, dichloromethane solution of 1'-bis (diphenylphosphine) ferrocene; Step 3: add the ethanol solution of chloropalladium sodium in step 1 Dropwise to step 2 under stirring condition, 1 '-bis (diphenylphosphine) ferrocene in methylene chloride solution, under the condition of the temperature of 25 deg C stirring reaction for 1H, after the reaction is filtered, 5.01g of crystals of orange-red [1,1'-bis (diphenylphosphino) ferrocene] Palladium dichloride dichloromethane complex are obtained in a yield of 90.46%. In this method, the target product of the solvent complex [1,1 '-bis (diphenylphosphine) ferrocene] Palladium dichloromethane complex was synthesized directly with dichloromethane as solvent in one step, the synthesis process of the precursor PdCl2(dppf) was omitted. The reaction process was simple, the synthesis cycle was short, and the operation was easy. The purity of the synthesized product was 99.4%, and the yield was 90.46%. |
| Application | catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction. |
Last Update：2024-04-09 19:05:15
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View History
95464-05-4
PT2385
SILICA REAGENT NO 2
UNII-7C247FL5FG
2-METHYLPROPYL BETA-PHENYLACRYLATE
4-Methoxycinnamic acid,predominantly trans
C.I. Acid Yellow 36 monosodium salt
s-Third
Hydroxy-PEG6-acid
Olaparib
PT2385
SILICA REAGENT NO 2
UNII-7C247FL5FG
2-METHYLPROPYL BETA-PHENYLACRYLATE
4-Methoxycinnamic acid,predominantly trans
C.I. Acid Yellow 36 monosodium salt
s-Third
Hydroxy-PEG6-acid
Olaparib