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TETRALIN(R)

1,2,3,4-Tetrahydronaphthalene

CAS: 119-64-2

Molecular Formula: C10H12

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TETRALIN(R) - Names and Identifiers

Name 1,2,3,4-Tetrahydronaphthalene
Synonyms THN
TETRALIN
Tetralin
TETRANAP
TETRALINE
TETRALIN(R)
tetralin solvent
1,2,3,4-tetrahydronaphthalin
1,2,3,4-Tetrahydronaphthalene
1,2,3,4-tetrahydro-naphthalen
1,2,3,4-Tetrahydronaphythalene
CAS 119-64-2
EINECS 204-340-2
InChI InChI=1/C10H12/c1-2-6-10-8-4-3-7-9(10)5-1/h1-2,5-6H,3-4,7-8H2

TETRALIN(R) - Physico-chemical Properties

Molecular FormulaC10H12
Molar Mass132.2
Density0.973 g/mL at 25 °C (lit.)
Melting Point-35 °C (lit.)
Boling Point207 °C (lit.)
Flash Point171°F
Water SolubilityINSOLUBLE
Solubility 0.045g/l
Vapor Presure0.18 mm Hg ( 20 °C)
Vapor Density4.55 (vs air)
AppearanceFluid
ColorColorless
Merck14,9221
BRN1446407
Storage ConditionStore below +30°C.
StabilityStable. Combustible. Incompatible with strong oxidizing agents.
SensitiveAir Sensitive
Explosive Limit0.8%, 100°F
Refractive Indexn20/D 1.541(lit.)
Physical and Chemical PropertiesThis product is a colorless liquid, has a stimulating odor, M. P.-35 ℃, B. p.207 ℃,n20D 1.5410, relative density 0.9730,f. P. 77 ℃, insoluble in water, soluble in ethanol, ether, acetone, acetic acid, benzene and petroleum ether.
UseUsed as solvent and chromatographic analysis reagent

TETRALIN(R) - Risk and Safety

Risk CodesR19 - May form explosive peroxides
R36/38 - Irritating to eyes and skin.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R65 - Harmful: May cause lung damage if swallowed
R40 - Limited evidence of a carcinogenic effect
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 - After contact with skin, wash immediately with plenty of soap-suds.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
S28A -
S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S36/37 - Wear suitable protective clothing and gloves.
UN IDsUN 3082 9/PG 3
WGK Germany2
RTECSQK3850000
TSCAYes
HS Code2902 90 00
Hazard Class9
Packing GroupIII
ToxicityLD50 orally in rats: 2.86 g/kg (Smyth)

TETRALIN(R) - Nature

Open Data Verified Data

colorless liquid with irritating odor. Melting Point -36 °c. Boiling point 206~207 deg C. Relative density 0.971, 0.9659. Refractive index 54614. The vapor pressure was 133 at 38 °c. Its vapor is 3.6 times heavier than air. Specific heat capacity 1. 69J/(g. °C)(18 °c). The heat of vaporization was 331 J/g. The heat of combustion was 5660 kJ/mol. Insoluble in water, soluble in ethanol, ether, acetone, acetic acid, benzene and petroleum ether. Flash point (closed) 71.2 °c. The explosion limit in air is 0. 8~6 ~ s%(volume).

Last Update:2025-06-10 22:55:16

TETRALIN(R) - Preparation Method

Open Data Verified Data

prepared from the selective hydrogenation of naphthalene over a nickel catalyst. Nickel molybdate was used as catalyst for gas phase catalytic reaction in an adiabatic reactor at a pressure of 2. 94MPA and a reaction temperature of 300 ℃. Feed space velocity was 0.8 h. The ratio of hydrogen to naphthalene is 2500 to 6400 by volume, the conversion rate of naphthalene per pass is 85%, and the selectivity is above 92%. The purity of tetrahydronaphthalene is more than 98% after distillation by gas stripping.

Last Update:2022-01-01 10:40:00

TETRALIN(R) - Application

Open Data Verified Data

A large number of used in the manufacture of insecticide carbaryl intermediate cresol; Also used in the manufacture of lubricants, and used to reduce the viscosity of high viscosity oil, and widely used as organic (resin, wax, grease, paint, plastic, etc.) of the solvent. It can also be used in the gas industry to dissolve, remove naphthalene deposition in the equipment, and as a liquid for washing gas. It is mixed with alcohol and benzene as a fuel for internal combustion engines. In addition, it can be used as a degreasing agent, a softener, an absorbent of low boiling point organic compound vapor, an insect repellent and a substitute for turpentine.

Last Update:2025-08-19 16:24:40

TETRALIN(R) - Safety

Open Data Verified Data
  • little toxicity, there is a certain anesthetic effect, can cause Head Pain, discomfort and skin eczema. Mouse oral LD50 2900mg/kg. The allowable concentration in air was 0.05 mg/kg. Tetrahydronaphthalene and air contact for a long time can generate hydrogen peroxide tetrahydronaphthalene caused an explosion, the use of must wear goggles, gas masks and rubber gloves.
  • tetrahydronaphthalene is a third-grade flammable liquid with fire hazard. Must be stored in a cool, ventilated place, away from the heat source, fire, and oxidant stored separately, light light discharge, keep the package intact.
Last Update:2022-01-01 10:40:01

TETRALIN(R) - Reference Information

olfactory Threshold 0.0093ppm
LogP3.78 at 23℃
NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Application 1,2,3, 4-tetrahydronaphthalene is an important intermediate for the preparation of cresol, which can be used to synthesize, diphenoxylamine and other pesticides.
used as solvent and chromatographic analysis reagent
manganese was examined. Degreasing agent. Intermediates. Solvents for naphthalene, oils and resins
production method the preparation method is to use naphthalene as raw material, in the presence of nickel molybdate catalyst, pressure 2.9 MPa, the temperature was 300 ° C., The hydrogenation reaction was carried out in an adiabatic reaction apparatus, and the obtained crude product was subjected to rectification to obtain a product.
category flammable liquid
toxicity grade poisoning
Acute toxicity oral-rat LD50: 1571 mg/kg
stimulation data Skin-rabbit 500 mg severe; eye-rabbit 500 mg/24 h mild
explosive hazard characteristics explosive when mixed with air; explosive peroxide generated by long-term contact with air
flammability hazard characteristics flammability; Combustion stimulus smoke
storage and transportation characteristics The warehouse is ventilated and dried at low temperature; Add antioxidants such as hydroquinone
extinguishing agent dry powder, foam, sand, water
spontaneous combustion temperature 723 ° F.
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-10 22:29:15
TETRALIN(R)
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